Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties
文献类型:期刊论文
作者 | Zhang P ; Zhang L ; Lin SY ; Tang JK |
刊名 | inorganic chemistry
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出版日期 | 2013 |
卷号 | 52期号:11页码:6595-6602 |
关键词 | SINGLE-MOLECULE-MAGNET ATMOSPHERIC CO2 FIXATION NEAR-INFRARED NIR DY-III SLOW RELAXATION 3D-4F COMPLEXES SALEN-TYPE CLUSTERS FAMILY FIELD |
ISSN号 | 0020-1669 |
通讯作者 | tang jk |
中文摘要 | the reactions between a salen ligand n,n'-bis(3-methoxysalicylidene)-1,2-cyclohexanediamine (h2l) and different metal salts lead to the formation of four 3d-4f [mdy] and [mdy](2) (m = zn/cu) compounds, where the [mdy](2) can be considered as resulting from the assembly of two [mdy] building blocks. field induced single molecule magnet (smm) behavior was observed in [zndy] and [cudy] compounds with the effective suppression of fast quantum tunneling under a dc field. moreover, the [zndy](2) compound demonstrates typical smm behavior, which may originate from the high axial anisotropy of dy ions correlating to the change of coordination geometry and enhanced ferromagnetic interactions between dy ions via the coupling of two [dyzn] units. the result suggests the positive effects of coupling blocking units to enhance their smm behavior, presenting a promising strategy for constructing efficient heterometallic smms. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000320015700040 |
公开日期 | 2014-04-15 |
源URL | [http://ir.ciac.jl.cn/handle/322003/49810] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang P,Zhang L,Lin SY,et al. Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties[J]. inorganic chemistry,2013,52(11):6595-6602. |
APA | Zhang P,Zhang L,Lin SY,&Tang JK.(2013).Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties.inorganic chemistry,52(11),6595-6602. |
MLA | Zhang P,et al."Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties".inorganic chemistry 52.11(2013):6595-6602. |
入库方式: OAI收割
来源:长春应用化学研究所
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