中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties

文献类型:期刊论文

作者Zhang P ; Zhang L ; Lin SY ; Tang JK
刊名inorganic chemistry
出版日期2013
卷号52期号:11页码:6595-6602
关键词SINGLE-MOLECULE-MAGNET ATMOSPHERIC CO2 FIXATION NEAR-INFRARED NIR DY-III SLOW RELAXATION 3D-4F COMPLEXES SALEN-TYPE CLUSTERS FAMILY FIELD
ISSN号0020-1669
通讯作者tang jk
中文摘要the reactions between a salen ligand n,n'-bis(3-methoxysalicylidene)-1,2-cyclohexanediamine (h2l) and different metal salts lead to the formation of four 3d-4f [mdy] and [mdy](2) (m = zn/cu) compounds, where the [mdy](2) can be considered as resulting from the assembly of two [mdy] building blocks. field induced single molecule magnet (smm) behavior was observed in [zndy] and [cudy] compounds with the effective suppression of fast quantum tunneling under a dc field. moreover, the [zndy](2) compound demonstrates typical smm behavior, which may originate from the high axial anisotropy of dy ions correlating to the change of coordination geometry and enhanced ferromagnetic interactions between dy ions via the coupling of two [dyzn] units. the result suggests the positive effects of coupling blocking units to enhance their smm behavior, presenting a promising strategy for constructing efficient heterometallic smms.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000320015700040
公开日期2014-04-15
源URL[http://ir.ciac.jl.cn/handle/322003/49810]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhang P,Zhang L,Lin SY,et al. Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties[J]. inorganic chemistry,2013,52(11):6595-6602.
APA Zhang P,Zhang L,Lin SY,&Tang JK.(2013).Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties.inorganic chemistry,52(11),6595-6602.
MLA Zhang P,et al."Tetranuclear [MDy](2) Compounds and Their Dinuclear [MDy] (M = Zn/Cu) Building Units: Their Assembly, Structures, and Magnetic Properties".inorganic chemistry 52.11(2013):6595-6602.

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来源:长春应用化学研究所

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