Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method
文献类型：期刊论文
| 作者 | Liu F ; Wang L ; Zhang GC ; Zheng J ; Tang T |
| 刊名 | chemical research in chinese universities
 |
| 出版日期 | 2013 |
| 卷号 | 29期号:3页码:589-595 |
| 关键词 | H-SHAPED POLYSTYRENES GURP-PALMEN-PLOT MELT RHEOLOGY HYDROCARBON POLYMERS POLYBUTADIENES POLYDISPERSITY HYDROGENATION COPOLYMERS BUTADIENE DYNAMICS |
| ISSN号 | 1005-9040 |
| 通讯作者 | tang t |
| 中文摘要 | comb-like polyethylene(pe) was prepared via anionic polymerization combined with "graft-onto" process. the polybutadiene(pb) backbone underwent hydroxylation at 1,2-vinyl groups to obtain a controlled number of hydroxyl groups along the main chain. after the translation of hydroxyl groups to tosyl groups, a nucleophilic substitution by living anionic pb chains was achieved. the comb pe was finally obtained by the hydrogenation of the obtained unsaturated comb polymer. since the living anionic polymerization was used to prepare the backbones and the branch chains, molecular weight to molecular weight distribution(m-w/m(n)1.5) can be well-controlled in the final comb polymer, including the average number and length of branches. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320296900035 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49822]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu F,Wang L,Zhang GC,et al. Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method[J]. chemical research in chinese universities,2013,29(3):589-595. |
| APA | Liu F,Wang L,Zhang GC,Zheng J,&Tang T.(2013).Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method.chemical research in chinese universities,29(3),589-595. |
| MLA | Liu F,et al."Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method".chemical research in chinese universities 29.3(2013):589-595. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。