Ethylene polymerization and ethylene/hexene copolymerizaion with vandium catalysts bearing thiophenolphosphine ligands
文献类型：期刊论文
| 作者 | Zhang SW ; Li YG ; Lu LP ; Li YS |
| 刊名 | chinese journal of polymer science
 |
| 出版日期 | 2013 |
| 卷号 | 31期号:6页码:885-893 |
| 关键词 | OPENING METATHESIS POLYMERIZATION OLEFIN POLYMERIZATION STRUCTURAL-CHARACTERIZATION SYNDIOTACTIC POLYMER ALUMINUM COCATALYST METAL-CATALYSTS COMPLEXES NORBORNENE PROPYLENE BEHAVIOR |
| ISSN号 | 0256-7679 |
| 通讯作者 | li ys |
| 中文摘要 | vanadium(iii) complexes bearing thiophenol-phosphine ligands (2a-2b) (2-r-6-pph2-c6h2s) vcl2(thf)(2) (2a: r = h; 2b: r = me3si) were prepared from vcl3(thf)(3) by treating with 1.0 equiv of the ligand in tetrahydrofuran in the presence of excess triethylamine. the two complexes were characterized by ftir and mass spectra as well as elemental analyses. on activation with et2alcl, these complexes exhibited high catalytic activities (up to 22.1 kg pe/(mmol(v)center dot h center dot bar)) even at high temperature (70 a degrees c), and produced high molecular weight polymers with unimodal molecular weight distributions, indicating the polymerization took place in a single-site nature. this result may be attributed to benefits of introduction of second-row donor atoms for adjusting charge density of the vanadium centers. in addition, these complexes also exhibited high catalytic activities for ethylene/1-hexene copolymerization. catalytic activity, comonomer incorporation and polymer molecular weight can be controlled in a wide range by the variation of catalyst structure and the reaction parameters such as al/v molar ratio, comonomer feed concentration and polymerization reaction temperature. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000317985500005 |
| 公开日期 | 2014-04-15 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49838]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang SW,Li YG,Lu LP,et al. Ethylene polymerization and ethylene/hexene copolymerizaion with vandium catalysts bearing thiophenolphosphine ligands[J]. chinese journal of polymer science,2013,31(6):885-893. |
| APA | Zhang SW,Li YG,Lu LP,&Li YS.(2013).Ethylene polymerization and ethylene/hexene copolymerizaion with vandium catalysts bearing thiophenolphosphine ligands.chinese journal of polymer science,31(6),885-893. |
| MLA | Zhang SW,et al."Ethylene polymerization and ethylene/hexene copolymerizaion with vandium catalysts bearing thiophenolphosphine ligands".chinese journal of polymer science 31.6(2013):885-893. |
入库方式： OAI收割
来源：长春应用化学研究所
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