Flexibility Improvement of Poly(L-lactide) by Reactive Blending With Poly(ether urethane) Containing Poly(ethylene glycol) Blocks
文献类型：期刊论文
| 作者 | Feng LD ; Bian XC ; Cui Y ; Chen ZM ; Li G ; Chen XS |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 2013 |
| 卷号 | 214期号:7页码:824-834 |
| 关键词 | POLY(LACTIC ACID) MECHANICAL-PROPERTIES ADIPATE-CO-TEREPHTHALATE) BLEND THERMAL CHARACTERIZATION TOUGHENING MODIFICATION POLY(PROPYLENE GLYCOL) SOYBEAN OIL COMPATIBILIZATION CRYSTALLIZATION PLASTICIZATION |
| ISSN号 | 1022-1352 |
| 通讯作者 | li g |
| 中文摘要 | poly(l-lactide) (plla) is melt blended with poly(ether urethane) (peu) based on poly(ethylene glycol) blocks via a chain-extension reaction by diisocyanate as a chain extender to improve its flexibility without sacrificing comprehensive performance. the elongation at break of the blends with triphenyl phosphate (tpp) as a reactive blending additive is much higher than that without tpp by physical blending. when 10 wt% peu is blended, the former elongation reaches to 298%, while the latter one is only approximately 20%. the reactive blending forms a pllapeu block copolymer, thus improving their compatibility. when the weight-average molecular weight (mw) of peus is 1890 kg mol1, the effect of mw is very little on tensile properties of blends. the rheological properties of the blends are modified through the content and molecular weight of peu. the complex viscosity (*) of plla/peu blends increases with increasing mw of peu. the * of the plla blend containing 5 wt% peu in mw 73 kg mol1 is higher than that of neat plla. the water absorption of the plla/peu blends enhances because of the hydrophilicity of peus versus neat plla. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000317083600008 |
| 公开日期 | 2014-04-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49918]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Feng LD,Bian XC,Cui Y,et al. Flexibility Improvement of Poly(L-lactide) by Reactive Blending With Poly(ether urethane) Containing Poly(ethylene glycol) Blocks[J]. macromolecular chemistry and physics,2013,214(7):824-834. |
| APA | Feng LD,Bian XC,Cui Y,Chen ZM,Li G,&Chen XS.(2013).Flexibility Improvement of Poly(L-lactide) by Reactive Blending With Poly(ether urethane) Containing Poly(ethylene glycol) Blocks.macromolecular chemistry and physics,214(7),824-834. |
| MLA | Feng LD,et al."Flexibility Improvement of Poly(L-lactide) by Reactive Blending With Poly(ether urethane) Containing Poly(ethylene glycol) Blocks".macromolecular chemistry and physics 214.7(2013):824-834. |
入库方式： OAI收割
来源：长春应用化学研究所
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