中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand

文献类型:期刊论文

作者Tian JM ; Li WL ; Li B ; Zhang XY ; Tang JK ; Zhang JP
刊名chemistry-a european journal
出版日期2013
卷号19期号:16页码:5097-5103
关键词METAL-ORGANIC FRAMEWORK SINGLE-CHAIN MAGNET CRYSTAL TRANSFORMATION SLOW RELAXATION SELECTIVE GAS ADSORPTION MOLECULES TOPOLOGY BEHAVIOR SERIES
ISSN号0947-6539
通讯作者zhang jp
中文摘要we have synthesized a microporous magnetic framework that contained supertetrahedral decametallic cobalt clusters as nodes and 4-(tris(hydroxymethyl)methyl)pyridine ligands as linkers in a nacl-like network. this complex shows canted antiferromagnetism with spin-glass behavior. after the removal of the guest molecules, the spin-canting and spin-glass behaviors are maintained. the permanent porosity was evaluated by n2-adsorption measurements. this complex mainly shows a hydrophobic nature, as validated by meoh- and water-adsorption measurements, which is consistent with the grand canonical monte carlo (gcmc) theoretical simulation.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000317399600020
公开日期2014-04-16
源URL[http://ir.ciac.jl.cn/handle/322003/49935]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Tian JM,Li WL,Li B,et al. Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand[J]. chemistry-a european journal,2013,19(16):5097-5103.
APA Tian JM,Li WL,Li B,Zhang XY,Tang JK,&Zhang JP.(2013).Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand.chemistry-a european journal,19(16),5097-5103.
MLA Tian JM,et al."Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand".chemistry-a european journal 19.16(2013):5097-5103.

入库方式: OAI收割

来源:长春应用化学研究所

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