Synthesis of well-defined comb-like graft (co)polymers by nucleophilic substitution reaction between living polymers and polyhalohydrocarbon
文献类型：期刊论文
| 作者 | Lin YC ; Zheng J ; Liu F ; Tang T |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 51期号:7页码:1664-1671 |
| 关键词 | ANIONIC-POLYMERIZATION BRANCHED POLYMERS COUPLING REACTION FUNCTIONALIZED POLYMERS ONTO METHODOLOGY COPOLYMERS STAR CRYSTALLIZATION POLYBUTADIENES POLYSTYRENES |
| ISSN号 | 0887-624x |
| 通讯作者 | tang t |
| 中文摘要 | a series of graft (co)polymers were synthesized by nucleophilic substitution reaction between iodinated 1,2-polybutadiene (pb-i, backbone) and living polymer lithium (side chains). the coupling reaction between pb-i and living polymers can finish within minutes at room temperature, and high conversion (up to 92%) could be obtained by effectively avoiding side reaction of dimerization when living polymers were capped with 1,1-diphenylethylene. by virtue of living anionic polymerization, backbone length, side chain length, and side chain composition, as well as graft density, were well controlled. tunable molecular weight of graft (co)polymers with narrow molecular weight distribution can be obtained by changing either the lengths of side chain and backbone, or the graft density. graft copolymers could also be synthesized with side chains of multicomponent polymers, such as block polymer (polystyrene-b-polybutadiene) and even mixed polymers (polystyrene and polybutadiene) as hetero chains. thus, based on living anionic polymerization, this work provides a facile way for modular synthesis of graft (co)polymers via nucleophilic substitution reaction between living polymers and polyhalohydrocarbon (pb-i). (c) 2013 wiley periodicals, inc. j polym sci part a: polym chem, 2013, 51, 1664-1671 |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000315495100021 |
| 公开日期 | 2014-04-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49956]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin YC,Zheng J,Liu F,et al. Synthesis of well-defined comb-like graft (co)polymers by nucleophilic substitution reaction between living polymers and polyhalohydrocarbon[J]. journal of polymer science part a-polymer chemistry,2013,51(7):1664-1671. |
| APA | Lin YC,Zheng J,Liu F,&Tang T.(2013).Synthesis of well-defined comb-like graft (co)polymers by nucleophilic substitution reaction between living polymers and polyhalohydrocarbon.journal of polymer science part a-polymer chemistry,51(7),1664-1671. |
| MLA | Lin YC,et al."Synthesis of well-defined comb-like graft (co)polymers by nucleophilic substitution reaction between living polymers and polyhalohydrocarbon".journal of polymer science part a-polymer chemistry 51.7(2013):1664-1671. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。