Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies
文献类型：期刊论文
| 作者 | Yang WT ; Tian T ; Wu HY ; Pan QJ ; Dang S ; Sun ZM |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 52期号:5页码:2736-2743 |
| 关键词 | BOND-VALENCE PARAMETERS CRYSTAL-STRUCTURES URANIUM(VI) CARBOXYPHOSPHONATES CATALYZED TRANSFORMATION ION-EXCHANGE DIPHOSPHONATES COMPLEXES CHAIN PHENYLPHOSPHONATE COORDINATION |
| ISSN号 | 0020-1669 |
| 通讯作者 | pan qj |
| 中文摘要 | six uranyl phosphonates and sulfonates have been hydrothermally synthesized, namely, (h(2)tib)[(uo2)(3)(po3c6h5)(4)]center dot 2h(2)o (uphp-1), zn(pi)(2)(uo2)(po3c6h5)(2) (uphp-2), zn(dib)(uo2)(po3c6h5)(2)center dot 2h(2)o (uphp-3), (htea)[(uo2)(5-sp)] (usp-1), (hdib)(2)[(uo2)(2)(oh)(o)(5-sp)] (usp-2), and zn(phen)(3)(uo2)(2)(3-sp)(2) (usp-3) (tib = 1,3,5-tri(1h-imidazol-1-yl)benzene, pi = 1-phenyl-1h-imidazole, dib = 1,4-di(1h-imidazol-1-yl)benzene, tea = triethylamine, phen = 1,10-phenanthroline, 5-sp = 5-sulfoisophthalic acid, and 3-sp = 3-sulfoisophthalic acid). uphp-1 has been determined to be a layered structure constructed by uo7 pentagonal bipyramids, uo6 octahedra, and phenylphosphonates. protonated tib plays a role in balancing the negative charge and holding its structure together. uphp-2 is made up of uo6 octahedra, zno2n2 tetrahedra and po3c tetrahedra in phenylphosphonates, forming a id assembly, which is stabilized by chelate phen ligand. further connection of such chainlike structure via dib yields a 2d layered architecture of uphp-3. although sulfonate group possesses similar tetrahedral structure as the phosphonate group, a unidentated coordination mode is only found in this work. uo7 pentagonal bipyramids are linked by 5-sp to form the layered assembly of usp-1. usp-2 also consists of the same sulfonate ligand, but features tetranulear uranyl clusters. similarly, protonated tea and dib molecules enable stabilization of their structures, respectively. formed by dinuclear uranyl cluster and 3-sp ligand, usp-3 appears as a 1d arrangement, in which zn(phen)(3) acts as the counterion to compensate the negative charge. all of these compounds have been characterized by ir and photoluminescent spectroscopy. their characteristic emissions have been attributed as transition properties of uranyl cations. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000315763300059 |
| 公开日期 | 2014-04-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49991]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang WT,Tian T,Wu HY,et al. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies[J]. inorganic chemistry,2013,52(5):2736-2743. |
| APA | Yang WT,Tian T,Wu HY,Pan QJ,Dang S,&Sun ZM.(2013).Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies.inorganic chemistry,52(5),2736-2743. |
| MLA | Yang WT,et al."Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies".inorganic chemistry 52.5(2013):2736-2743. |
入库方式： OAI收割
来源：长春应用化学研究所
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