Investigation of Pt nanoparticles with controlled size supported on carbon for dimethyl ether electrooxidation
文献类型:期刊论文
作者 | Si FZ ; Liao JH ; Liang L ; Liu CP ; Zhang XB ; Xing W |
刊名 | journal of power sources
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出版日期 | 2013 |
卷号 | 225页码:231-239 |
关键词 | SINGLE-CRYSTAL ELECTRODES FUEL-CELLS PARTICLE-SIZE ALTERNATIVE FUEL CATALYSTS PT/C ACID DME MECHANISM METHANOL |
ISSN号 | 0378-7753 |
通讯作者 | xing w |
中文摘要 | a series of pt/c catalysts with controlled pt particle sizes is synthesized using a surfactant-free process with ethylene glycol as the weak reducing agent. the pt particle size can be regulated by controlling the ph of the pt (iv) complex via the addition of different amounts of urea. the results of x-ray diffraction and transmission electron microscopy confirm that the pt nanoparticles on the carbon exhibit good size controllability and dispersion. the electroactive surface area (esa), the electron transfer coefficient, and the electrocatalytic activity to dimethyl ether electrooxidation are dependent on the pt particle size, and a comparison of the electrochemical properties of the samples reveals that the relationships are parabolic. the results are important for understanding the mechanism of and designing an effective catalyst for dimethyl ether (dme) electrooxidation and providing a size-controlled synthetic method for pt-based catalysts. (c) 2012 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000313923400035 |
公开日期 | 2014-04-16 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50016] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Si FZ,Liao JH,Liang L,et al. Investigation of Pt nanoparticles with controlled size supported on carbon for dimethyl ether electrooxidation[J]. journal of power sources,2013,225:231-239. |
APA | Si FZ,Liao JH,Liang L,Liu CP,Zhang XB,&Xing W.(2013).Investigation of Pt nanoparticles with controlled size supported on carbon for dimethyl ether electrooxidation.journal of power sources,225,231-239. |
MLA | Si FZ,et al."Investigation of Pt nanoparticles with controlled size supported on carbon for dimethyl ether electrooxidation".journal of power sources 225(2013):231-239. |
入库方式: OAI收割
来源:长春应用化学研究所
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