Effect of structure of CuO/ZnO/Al2O3 composites on catalytic performance for hydrogenation of fatty acid ester
文献类型：期刊论文
| 作者 | He LM ; Cheng HY ; Liang GF ; Yu YC ; Zhao FY |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2013 |
| 卷号 | 452页码:88-93 |
| 关键词 | ZINC-OXIDE CATALYSTS GAS SHIFT REACTION METHANOL SYNTHESIS CU/ZNO/AL2O3 CATALYST ACTIVE-SITE MECHANISM ALCOHOLS MICROSTRUCTURE NANOPARTICLES DECOMPOSITION |
| ISSN号 | 0926-860x |
| 通讯作者 | zhao fy |
| 中文摘要 | in this work, cuo/zno/al2o3 catalysts were prepared by adjusting the initial alkali concentration in the process of co-precipitation. the correlation between the structure and catalytic activity was studied, and the catalyst derived from ldhs (layered double hydroxides) structure exhibited the highest activity in the hydrogenation of fatty esters as well as high selectivity to fatty alcohol, producing fatty alcohol with a yield above 98%. the high catalytic performance was attributed to relatively high dispersion (small crystal size) and the high reducibility of copper species. in addition, the active species was discussed and the cu+/cu-0 were supposed to be the active site for the present hydrogenation. (c) 2012 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000315013200013 |
| 公开日期 | 2014-04-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50037]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | He LM,Cheng HY,Liang GF,et al. Effect of structure of CuO/ZnO/Al2O3 composites on catalytic performance for hydrogenation of fatty acid ester[J]. applied catalysis a-general,2013,452:88-93. |
| APA | He LM,Cheng HY,Liang GF,Yu YC,&Zhao FY.(2013).Effect of structure of CuO/ZnO/Al2O3 composites on catalytic performance for hydrogenation of fatty acid ester.applied catalysis a-general,452,88-93. |
| MLA | He LM,et al."Effect of structure of CuO/ZnO/Al2O3 composites on catalytic performance for hydrogenation of fatty acid ester".applied catalysis a-general 452(2013):88-93. |
入库方式： OAI收割
来源：长春应用化学研究所
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