Exponentially increased nucleation ability for poly(L-lactide) by adding acid-oxidized multiwalled carbon nanotubes with reduced aspect ratios
文献类型:期刊论文
作者 | Zhong Y ; Zhang YQ ; Yang JJ ; Li WL ; Wang ZG ; Xu DH ; Chen SY ; Ding YS |
刊名 | science china-chemistry
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出版日期 | 2013 |
卷号 | 56期号:2页码:181-194 |
关键词 | POLY(LACTIC ACID) THERMOMECHANICAL PROPERTIES CRYSTALLIZATION BEHAVIOR ELECTRICAL-CONDUCTIVITY MECHANICAL-PROPERTIES MELT-CRYSTALLIZATION COMPOSITES POLYPROPYLENE FUNCTIONALIZATION NANOCOMPOSITES |
ISSN号 | 1674-7291 |
通讯作者 | wang zg |
中文摘要 | acid-oxidized multiwalled carbon nanotubes (a-mwcnts) with a range of reduced aspect ratios (from about 11 to 5.8) were obtained by acid oxidization of mwcnts in the mixture of hno3 and h2so4 for varying periods of 1, 3, 8 and 12 h, respectively. the aspect ratios and surface functionalization of a-mwcnts were well characterized by scanning electron microscopy (sem), fourier transform infrared spectroscopy (ftir), raman spectroscopy and thermogravimetric analysis (tga). poly(l-lactide)/a-mwcnt composites containing 0.5 wt% a-mwcnts with a range of reduced aspect ratios were prepared by solution cast. the effects of added a-mwcnts on the isothermal crystallization kinetics of poly(l-lactide)/a-mwcnt composites were investigated by means of differential scanning calorimetry (dsc), rheology and polarized optical microscopy (pom). it is surprising to find that not only the addition of a-mwcnts effectively increases the poly(l-lactide) (pla) crystallization kinetics, but also the nucleation ability of a-mwcnts for pla crystallization exponentially increases with the reduced aspect ratio, that is to say, those with lower aspect ratios show much stronger nucleation ability for pla crystallization than those with higher aspect ratios. the exponentially increased nucleation ability of a-mwcnts with a range of reduced aspect ratios for pla crystallization is disclosed. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000314271900004 |
公开日期 | 2014-04-16 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50074] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhong Y,Zhang YQ,Yang JJ,et al. Exponentially increased nucleation ability for poly(L-lactide) by adding acid-oxidized multiwalled carbon nanotubes with reduced aspect ratios[J]. science china-chemistry,2013,56(2):181-194. |
APA | Zhong Y.,Zhang YQ.,Yang JJ.,Li WL.,Wang ZG.,...&Ding YS.(2013).Exponentially increased nucleation ability for poly(L-lactide) by adding acid-oxidized multiwalled carbon nanotubes with reduced aspect ratios.science china-chemistry,56(2),181-194. |
MLA | Zhong Y,et al."Exponentially increased nucleation ability for poly(L-lactide) by adding acid-oxidized multiwalled carbon nanotubes with reduced aspect ratios".science china-chemistry 56.2(2013):181-194. |
入库方式: OAI收割
来源:长春应用化学研究所
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