Copper nanoclusters as peroxidase mimetics and their applications to H2O2 and glucose detection
文献类型:期刊论文
作者 | Hu LZ ; Yuan YL ; Zhang L ; Zhao JM ; Majeed S ; Xu GB |
刊名 | analytica chimica acta
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出版日期 | 2013 |
卷号 | 762页码:83-86 |
关键词 | FLUORESCENT DETECTION GOLD NANOPARTICLES CLUSTERS SENSOR ION |
ISSN号 | 0003-2670 |
通讯作者 | xu gb |
中文摘要 | copper nanoclusters (cu ncs) are found to possess intrinsic peroxidase-like activity for the first time. similar to nature peroxidase, they can catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine by h2o2 to produce a nice blue color reaction. compared with horseradish peroxidase, cu ncs exhibits higher activity near neutral ph, which is beneficial for biological applications. the increase in absorbance caused by the cu ncs catalytic reaction allows the detection of h2o2 in the range of 10 mu m to 1 mm with a detection limit of 10 mu m. a calorimetric method for glucose detection was also developed by combining the cu ncs catalytic reaction and the enzymatic oxidation of glucose with glucose oxidase. taking into account the advantages of ultra-small size, good stability, and high biocompatibility in aqueous solutions, cu ncs are expected to have potential applications in biotechnology and clinical diagnosis as enzymatic mimics. (c) 2012 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000314441300010 |
公开日期 | 2014-04-16 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50083] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Hu LZ,Yuan YL,Zhang L,et al. Copper nanoclusters as peroxidase mimetics and their applications to H2O2 and glucose detection[J]. analytica chimica acta,2013,762:83-86. |
APA | Hu LZ,Yuan YL,Zhang L,Zhao JM,Majeed S,&Xu GB.(2013).Copper nanoclusters as peroxidase mimetics and their applications to H2O2 and glucose detection.analytica chimica acta,762,83-86. |
MLA | Hu LZ,et al."Copper nanoclusters as peroxidase mimetics and their applications to H2O2 and glucose detection".analytica chimica acta 762(2013):83-86. |
入库方式: OAI收割
来源:长春应用化学研究所
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