A Template-Free and Surfactant-Free Method for High-Yield Synthesis of Highly Monodisperse 3-Aminophenol-Formaldehyde Resin and Carbon Nano/Microspheres
文献类型：期刊论文
| 作者 | Zhao JM ; Niu WX ; Zhang L ; Cai HR ; Han MY ; Yuan YL ; Majeed S ; Anjum S ; Xu GB |
| 刊名 | macromolecules
 |
| 出版日期 | 2013 |
| 卷号 | 46期号:1页码:140-145 |
| 关键词 | MAGNETIC-RESONANCE SILICA SHELL FORMALDEHYDE NANOSPHERES SPHERES NANOPARTICLES POLYMER ARRAYS NANOSTRUCTURE NANOCOMPOSITE |
| ISSN号 | 0024-9297 |
| 通讯作者 | xu gb |
| 中文摘要 | a template-free and surfactant-free method for the synthesis of highly monodisperse phenol formaldehyde resin and corresponding carbon nano/microspheres with excellent size tunability has been developed for the first time after investigating a series of phenol derivatives, including 3-methylphenol, 1,3,5-trihydroxybenzene, 2-aminophenol, 3-aminophenol, and 4-aminophenol. the method is based on the polymerization reaction of 3-aminophenol and formaldehyde in the mixture solutions of water and ethanol to generate 3-aminophenol/formaldehyde (apf) resin colloidal spheres. the sizes of apf resin colloidal spheres are tunable in a very broad range from 80 nm up to 2500 nm by changing reaction conditions. the excellent thermal stability of apf resins allows the generation of monodisperse carbon spheres by the pyrolysis of apf resin spheres with high yields. both apf resin spheres and corresponding carbon spheres are so monodisperse (polydispersity <3%) that can form three-dimensional periodic structures. the method has striking features of excellent monodispersity, very broad size tunability, high yield, smooth sphere surface, and easy preparation. this approach also holds great promise for the large-scale production of resin spheres and carbon spheres. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000313303600017 |
| 公开日期 | 2014-04-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50114]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao JM,Niu WX,Zhang L,et al. A Template-Free and Surfactant-Free Method for High-Yield Synthesis of Highly Monodisperse 3-Aminophenol-Formaldehyde Resin and Carbon Nano/Microspheres[J]. macromolecules,2013,46(1):140-145. |
| APA | Zhao JM.,Niu WX.,Zhang L.,Cai HR.,Han MY.,...&Xu GB.(2013).A Template-Free and Surfactant-Free Method for High-Yield Synthesis of Highly Monodisperse 3-Aminophenol-Formaldehyde Resin and Carbon Nano/Microspheres.macromolecules,46(1),140-145. |
| MLA | Zhao JM,et al."A Template-Free and Surfactant-Free Method for High-Yield Synthesis of Highly Monodisperse 3-Aminophenol-Formaldehyde Resin and Carbon Nano/Microspheres".macromolecules 46.1(2013):140-145. |
入库方式： OAI收割
来源：长春应用化学研究所
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