Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands
文献类型：期刊论文
| 作者 | Yi FY ; Dang S ; Yang WT ; Sun ZM |
| 刊名 | crystengcomm
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:41页码:8320-8329 |
| 关键词 | HYDROGEN-BONDED NETWORKS LUMINESCENT PROPERTIES COORDINATION POLYMERS ADSORPTION PROPERTIES MOLECULAR TECTONICS MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES LIGAND COMPLEXES ARCHITECTURES |
| ISSN号 | 1466-8033 |
| 通讯作者 | yi fy |
| 中文摘要 | solvothermal reactions of hexa[4-(carboxyphenyl) oxamethyl]-3-oxapentane (h6l) with rigid coligands, 2,2'-bipyridine (bipy), 1,4-bis-(1-imidazolyl) benzene (dib), and 4,4'-bis(1-imidazolyl) biphenyl (bibp) in the presence of manganese salts produce four porous mn(ii) metal-organic frameworks (mn-mofs), namely, mn-3(l)(bipy)(2) (1), mn-3(l)(dib) (2), mn-3(l)(dib)(h2o)(2) (3), and mn-6(l)(2)(bibp)(1.5)(h2o)(5) 4. single crystal x-ray diffraction analyses reveal that 1-4 consist of trinuclear mn-ii subunits, which are further connected into four interesting nets, 4,4-connected pts net for 1, 4,6-connected fsc net for 2, and two novel nets for 3 and 4, by the synergistic effect of carboxylate groups and functionally complementary n-donor ligands. they exhibit high potential solvent accessible volumes of 35.0%, 33.5%, 45.1%, and 56.5% for 1-4, respectively. magnetic studies indicate the presence of weak antiferromagnetic interactions between mn-ii centers in these compounds. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000325368300014 |
| 公开日期 | 2014-04-16 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50178]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yi FY,Dang S,Yang WT,et al. Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands[J]. crystengcomm,2013,15(41):8320-8329. |
| APA | Yi FY,Dang S,Yang WT,&Sun ZM.(2013).Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands.crystengcomm,15(41),8320-8329. |
| MLA | Yi FY,et al."Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands".crystengcomm 15.41(2013):8320-8329. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。