中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion

文献类型:期刊论文

作者Hao ZM ; Song XZ ; Zhu M ; Meng X ; Zhao SN ; Su SQ ; Yang WT ; Song SY ; Zhang HJ
刊名journal of materials chemistry a
出版日期2013
卷号1期号:36页码:11043-11050
关键词LANTHANIDE COORDINATION POLYMERS ELECTRICAL-CONDUCTIVITY SORPTION PROPERTIES SELECTIVE SORPTION SINGLE-CRYSTAL METAL SITES FRAMEWORK FLUORESCENCE CATALYSIS RELEASE
ISSN号2050-7488
通讯作者zhang hj
中文摘要two new lanthanide metal-organic frameworks ln(fbpt)(h2o)(dmf) (fbpt = 2'-fluoro-biphenyl-3,4',5-tricarboxylate, ln = eu and tb) were prepared under solvothermal conditions. single crystal x-ray diffraction analyses reveal that the two compounds are isostructurally related with the same one-dimensional channel structure on the basis of fbpt as an organic linker. herein, the eu(fbpt)(h2o)(dmf) (eul) is selected as a representative sample for luminescent measurements. study of the photoluminescence properties reveals that the eul exhibits red emission, corresponding to the d-5(0) -> f-7(j) (j = 1-4) transitions of the eu3+ ion under uv light excitation. most interestingly, when this compound was immersed in the different organic solvents and metal ion dmf solutions, it shows highly selective and sensitive sensing for small organic molecules and cu2+ ions. in connection to this, a probable sensing mechanism was also discussed in this paper.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000323276200059
公开日期2014-04-16
源URL[http://ir.ciac.jl.cn/handle/322003/50205]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Hao ZM,Song XZ,Zhu M,et al. One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion[J]. journal of materials chemistry a,2013,1(36):11043-11050.
APA Hao ZM.,Song XZ.,Zhu M.,Meng X.,Zhao SN.,...&Zhang HJ.(2013).One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion.journal of materials chemistry a,1(36),11043-11050.
MLA Hao ZM,et al."One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion".journal of materials chemistry a 1.36(2013):11043-11050.

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来源:长春应用化学研究所

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