Functional microporous polyimides based on sulfonated binaphthalene dianhydride for uptake and separation of carbon dioxide and vapors
文献类型：期刊论文
| 作者 | Yang YQ ; Zhang Q ; Zhang ZG ; Zhang SB |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2013 |
| 卷号 | 1期号:35页码:10368-10374 |
| 关键词 | HIGH-SURFACE-AREA COVALENT ORGANIC FRAMEWORKS PROTON-EXCHANGE MEMBRANES NANOPOROUS MATERIALS HYDROGEN STORAGE GAS-STORAGE POLYMERS ADSORPTION METHANE CATALYSIS |
| ISSN号 | 2050-7488 |
| 通讯作者 | zhang sb |
| 中文摘要 | a series of novel microporous polyimides (smpis) were synthesized from 4,4'-binaphthyl-1,1',8,8'-tetracarboxylic dianhydride (btda), 6,6'-disulfonic-4,4'-binaphthyl-1,1',8,8'-tetracarboxylic dianhydride (sbtda) and tetrakis(4-aminophenyl)methane (tapm). the non-sulfonated smpi-0 (smpi-x, where "x" is the molar percent of sbtda) exhibited a bet surface area of 574 m(2) g(-1) and a co2 uptake of 2.53 mmol g(-1), while sulfonated samples, i.e. smpi-10, smpi-50 and smpi-100, possessed relatively low bet surface areas (from 23 to 112 m(2) g(-1)) but high co2 capture capacities (from 2.82 to 3.15 mmol g(-1)) and co2/n-2 selectivities (from 32 to 57). with the increase of sulfonation degree, the polymers were graded from hydrophobic to hydrophilic. hydrophobic smpi-0 and smpi-10 adsorbed a large amount of non-polar benzene (134.7 wt% for smpi-0 and 104.7 wt% for smpi-10) and cyclohexane (42.5 wt% for smpi-0 and 42.8 wt% for smpi-10) vapor, whereas hydrophilic smpi-50 and smpi-100 adsorbed more polar methanol (68.5 wt% for smpi-50 and 72.2 wt% for smpi-100). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000323132700039 |
| 公开日期 | 2014-04-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50213]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang YQ,Zhang Q,Zhang ZG,et al. Functional microporous polyimides based on sulfonated binaphthalene dianhydride for uptake and separation of carbon dioxide and vapors[J]. journal of materials chemistry a,2013,1(35):10368-10374. |
| APA | Yang YQ,Zhang Q,Zhang ZG,&Zhang SB.(2013).Functional microporous polyimides based on sulfonated binaphthalene dianhydride for uptake and separation of carbon dioxide and vapors.journal of materials chemistry a,1(35),10368-10374. |
| MLA | Yang YQ,et al."Functional microporous polyimides based on sulfonated binaphthalene dianhydride for uptake and separation of carbon dioxide and vapors".journal of materials chemistry a 1.35(2013):10368-10374. |
入库方式： OAI收割
来源：长春应用化学研究所
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