Three dinuclear lanthanide(III) compounds of a polydentate Schiff base ligand: Slow magnetic relaxation behaviour of the Dy-III derivative
文献类型：期刊论文
| 作者 | Zhao L ; Wu JF ; Ke HS ; Tang JK |
| 刊名 | crystengcomm
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:26页码:5301-5306 |
| 关键词 | SINGLE-MOLECULE-MAGNET GADOLINIUM CARBOXYLATES CRYSTAL-STRUCTURE DOMAIN-WALL ANISOTROPY COMPLEX DESIGN PARAMETERS CLUSTERS EXCHANGE |
| ISSN号 | 1466-8033 |
| 通讯作者 | zhao l |
| 中文摘要 | the initial employment of n-1,n-2,n-3,n-4-tri(3-methoxysalicylidene) triethylenetetraamine ligand (h3l, scheme 1) in lanthanide coordination chemistry for single molecule magnets has yielded a new family of dinuclear ln(2)(iii) compounds with the general formula of [ln(2)(l)(2)]center dot nch(3)cn (ln = gd (1), tb (2) with n = 0, ln = dy (3) with n = 4). these three complexes have been structurally and magnetically characterized. the structural analyses reveal that they are isomorphous dinuclear complexes where the ln(2) entities were encapsulated by two polydentate schiff base ligands. variable-temperature magnetic susceptibility studies indicate the presence of dominant antiferromagnetic interactions in complexes 2 and 3, whereas complex 1 containing isotropic gd ions allows the quantification of the antiferromagnetic interaction with j(gd-gd) = -0.041 cm(-1). dynamic measurements reveal that 3 displays single-molecule magnet behaviour with an activation energy barrier delta = 18.9 k and pre-exponential factor tau(0) = 3.92 x 10(-6) s, while 1 and 2 do not show any out-of-phase ac susceptibility signals. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320223900014 |
| 公开日期 | 2014-04-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50268]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao L,Wu JF,Ke HS,et al. Three dinuclear lanthanide(III) compounds of a polydentate Schiff base ligand: Slow magnetic relaxation behaviour of the Dy-III derivative[J]. crystengcomm,2013,15(26):5301-5306. |
| APA | Zhao L,Wu JF,Ke HS,&Tang JK.(2013).Three dinuclear lanthanide(III) compounds of a polydentate Schiff base ligand: Slow magnetic relaxation behaviour of the Dy-III derivative.crystengcomm,15(26),5301-5306. |
| MLA | Zhao L,et al."Three dinuclear lanthanide(III) compounds of a polydentate Schiff base ligand: Slow magnetic relaxation behaviour of the Dy-III derivative".crystengcomm 15.26(2013):5301-5306. |
入库方式： OAI收割
来源：长春应用化学研究所
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