Preparation and Characterization of PMMA/MMT Organic-Inorganic Hybrid Materials via RAFT Polymerization
文献类型：期刊论文
| 作者 | Ma JY ; Lu MG ; Cao CL ; Zhang HX |
| 刊名 | journal of macromolecular science part a-pure and applied chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 50期号:6页码:653-660 |
| 关键词 | SILICA NANOPARTICLES NANOCOMPOSITE PARTICLES RADICAL POLYMERIZATION SURFACE POLYSTYRENE COMPOSITES MINIEMULSION DISPERSION MECHANISM STRATEGY |
| ISSN号 | 1060-1325 |
| 通讯作者 | ma jy |
| 中文摘要 | in this article, the poly(methyl methacrylate)/montmorillonite (pmma/mmt) organic-inorganic hybrid materials were prepared by conventional free radical polymerization and reversible addition-fragmentation chain transfer (raft) polymerization, respectively. the kinetics comparison of these two polymerizations was studied. the pmma/mmt hybrid materials were characterized by gel permeation chromatography (gpc), differential scanning calorimetry (dsc) and thermogravimetric analysis (tga). according to these results, we knew that the polymerization behavior of mma showed controlled/living radical polymerization (clrp) characteristics under the control of raft agent. the incorporation of raft agent and mmt nanoparticles improved the thermal properties of polymers, and the thermal stability of polymers increased with increasing content of mmt nanoparticles. the structures and morphologies of pmma/mmt hybrid materials were characterized by ft-ir, xrd and tem. these results showed that the mma monomer can be initiated and propagated in the clay layers of mmt via the control of raft agent, and then the exfoliated structure was obtained for the hybrid materials. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000317905600011 |
| 公开日期 | 2014-04-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50304]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ma JY,Lu MG,Cao CL,et al. Preparation and Characterization of PMMA/MMT Organic-Inorganic Hybrid Materials via RAFT Polymerization[J]. journal of macromolecular science part a-pure and applied chemistry,2013,50(6):653-660. |
| APA | Ma JY,Lu MG,Cao CL,&Zhang HX.(2013).Preparation and Characterization of PMMA/MMT Organic-Inorganic Hybrid Materials via RAFT Polymerization.journal of macromolecular science part a-pure and applied chemistry,50(6),653-660. |
| MLA | Ma JY,et al."Preparation and Characterization of PMMA/MMT Organic-Inorganic Hybrid Materials via RAFT Polymerization".journal of macromolecular science part a-pure and applied chemistry 50.6(2013):653-660. |
入库方式： OAI收割
来源：长春应用化学研究所
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