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Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system
文献类型:期刊论文
作者 | Parveen S ; Zhang W ; Yuan YL ; Hu LZ ; Gilani MRHS ; Rehman AU ; Xu GB |
刊名 | journal of electroanalytical chemistry
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出版日期 | 2013 |
卷号 | 688页码:45-48 |
关键词 | TRIS(2 ELECTROCHEMILUMINESCENCE COMPLEXES 2'-BIPYRIDYL)RUTHENIUM(II) |
ISSN号 | 1572-6657 |
通讯作者 | rehman au |
中文摘要 | 2-(dibutylamino)ethanol (dbae) is a highly effective coreactant for ru(bpy)(3)(2-) electrochemiluminescence (ecl) and ru(phen)(3)(2+) is a well-known ecl luminophore. in this study, ecl of ru(phen)(3)(2+)/dbae has been investigated for the first time. this study has been carried out using cyclic voltametry and amperometry. the results imply that amperometry is found to be superior to cyclic voltametry as it shows approximately five fold enhancement in ecl emission intensity. furthermore, compared to ru(bpy)(3)(2+), ru(phen)(3)(2+) provides several fold increase in ecl intensities with dbae. sensitive detection of ru(phen)(3)(2+) is achieved with a linear range over approximately four orders of magnitude using very low concentration of dbae (5 mm). (c) 2012 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000317158800009 |
公开日期 | 2014-04-18 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50311] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Parveen S,Zhang W,Yuan YL,et al. Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system[J]. journal of electroanalytical chemistry,2013,688:45-48. |
APA | Parveen S.,Zhang W.,Yuan YL.,Hu LZ.,Gilani MRHS.,...&Xu GB.(2013).Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system.journal of electroanalytical chemistry,688,45-48. |
MLA | Parveen S,et al."Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system".journal of electroanalytical chemistry 688(2013):45-48. |
入库方式: OAI收割
来源:长春应用化学研究所
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