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Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system

文献类型:期刊论文

作者Parveen S ; Zhang W ; Yuan YL ; Hu LZ ; Gilani MRHS ; Rehman AU ; Xu GB
刊名journal of electroanalytical chemistry
出版日期2013
卷号688页码:45-48
关键词TRIS(2 ELECTROCHEMILUMINESCENCE COMPLEXES 2'-BIPYRIDYL)RUTHENIUM(II)
ISSN号1572-6657
通讯作者rehman au
中文摘要2-(dibutylamino)ethanol (dbae) is a highly effective coreactant for ru(bpy)(3)(2-) electrochemiluminescence (ecl) and ru(phen)(3)(2+) is a well-known ecl luminophore. in this study, ecl of ru(phen)(3)(2+)/dbae has been investigated for the first time. this study has been carried out using cyclic voltametry and amperometry. the results imply that amperometry is found to be superior to cyclic voltametry as it shows approximately five fold enhancement in ecl emission intensity. furthermore, compared to ru(bpy)(3)(2+), ru(phen)(3)(2+) provides several fold increase in ecl intensities with dbae. sensitive detection of ru(phen)(3)(2+) is achieved with a linear range over approximately four orders of magnitude using very low concentration of dbae (5 mm). (c) 2012 elsevier b.v. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000317158800009
公开日期2014-04-18
源URL[http://ir.ciac.jl.cn/handle/322003/50311]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Parveen S,Zhang W,Yuan YL,et al. Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system[J]. journal of electroanalytical chemistry,2013,688:45-48.
APA Parveen S.,Zhang W.,Yuan YL.,Hu LZ.,Gilani MRHS.,...&Xu GB.(2013).Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system.journal of electroanalytical chemistry,688,45-48.
MLA Parveen S,et al."Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system".journal of electroanalytical chemistry 688(2013):45-48.

入库方式: OAI收割

来源:长春应用化学研究所

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