Striking influence of Fe2O3 on the "catalytic carbonization" of chlorinated poly(vinyl chloride) into carbon microspheres with high performance in the photo-degradation of Congo red
文献类型：期刊论文
| 作者 | Gong J ; Yao K ; Liu J ; Jiang ZW ; Chen XC ; Wen X ; Mijowska E ; Tian NN ; Tang T |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2013 |
| 卷号 | 1期号:17页码:5247-5255 |
| 关键词 | THERMAL-DEGRADATION ACTIVATED CARBON METAL-OXIDES POLYPROPYLENE NANOTUBES PVC DEHYDROCHLORINATION COMPOSITES COMBUSTION MECHANISM |
| ISSN号 | 2050-7488 |
| 通讯作者 | gong j |
| 中文摘要 | a one-pot approach was demonstrated to effectively synthesize carbon microspheres through "catalytic carbonization" of commercial chlorinated poly(vinyl chloride) (cpvc) microspheres by fe2o3 at 700 degrees c. without fe2o3, a "sponge-like" carbon lump was obtained. however, after adding fe2o3 (even 0.5 g per 100 g cpvc) into cpvc, carbon microspheres with octahedral fe3o4 microcrystals uniformly embedded on the surface (fe/cms) were synthesized. the influence of fe2o3 on the carbonization of cpvc microspheres was investigated. it was found that fe2o3 significantly accelerated the dehydrochlorination of cpvc into polyene before the melting of the cpvc microsphere surface. as a result, the microspheres of raw cpvc showed a "shape-duplicate" carbonization behaviour. the resultant fe/cms showed high photo-degradation efficiency of congo red under uv irradiation via a heterogeneous photo-fenton process with high recyclablity, reusability and long-term stability. this indicated that the resultant fe/cms has a potential application in wastewater treatment. therefore, the initial catalytic substance could be effectively used as a catalyst twice in the carbonization of cpvc microspheres and in the subsequent application of fe/cms. more importantly, the strategy of "catalytic carbonization" offers a new potential way to largely convert charring polymers into functional carbon and carbon-based materials with various morphologies. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000316968000009 |
| 公开日期 | 2014-04-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50323]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gong J,Yao K,Liu J,et al. Striking influence of Fe2O3 on the "catalytic carbonization" of chlorinated poly(vinyl chloride) into carbon microspheres with high performance in the photo-degradation of Congo red[J]. journal of materials chemistry a,2013,1(17):5247-5255. |
| APA | Gong J.,Yao K.,Liu J.,Jiang ZW.,Chen XC.,...&Tang T.(2013).Striking influence of Fe2O3 on the "catalytic carbonization" of chlorinated poly(vinyl chloride) into carbon microspheres with high performance in the photo-degradation of Congo red.journal of materials chemistry a,1(17),5247-5255. |
| MLA | Gong J,et al."Striking influence of Fe2O3 on the "catalytic carbonization" of chlorinated poly(vinyl chloride) into carbon microspheres with high performance in the photo-degradation of Congo red".journal of materials chemistry a 1.17(2013):5247-5255. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。