Facile and rapid synthesis of water-soluble fluorescent gold nanoclusters for sensitive and selective detection of Ag+
文献类型:期刊论文
作者 | Sun J ; Yue Y ; Wang P ; He HL ; Jin YD |
刊名 | journal of materials chemistry c
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出版日期 | 2013 |
卷号 | 1期号:5页码:908-913 |
关键词 | SILVER(I) IONS QUANTUM DOTS NANOPARTICLES CLUSTERS MERCURY(II) SENSOR SIZE HG2+ |
ISSN号 | 2050-7526 |
通讯作者 | sun j |
中文摘要 | we report a direct one-pot approach, employing tetrakis(hydroxymethyl)phosphonium chloride (thpc) and 11-mercaptoundecanoic acid (11-mua) as combined reducing/capping agents, for the rapid preparation of fluorescent gold nanoclusters (auncs) from haucl4 in aqueous solution at room temperature. the as-prepared auncs exhibit a fluorescence emission at 535 nm, a quantum yield of 1.8% and average diameters of 2.0 +/- 0.5 nm. the resultant mua/thpc-auncs have been exploited, for the first time, for the highly sensitive and selective detection of silver ions (ag+) in aqueous solution when using edta as a masking agent for hg2+. the fluorescence intensity quenches linearly within the range of 25 nm to 3 mu m with high sensitivity (lod = 9 nm, s/n = 3) and this sensing system has been applied for environmental water sample analysis. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000314803600005 |
公开日期 | 2014-04-18 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50380] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Sun J,Yue Y,Wang P,et al. Facile and rapid synthesis of water-soluble fluorescent gold nanoclusters for sensitive and selective detection of Ag+[J]. journal of materials chemistry c,2013,1(5):908-913. |
APA | Sun J,Yue Y,Wang P,He HL,&Jin YD.(2013).Facile and rapid synthesis of water-soluble fluorescent gold nanoclusters for sensitive and selective detection of Ag+.journal of materials chemistry c,1(5),908-913. |
MLA | Sun J,et al."Facile and rapid synthesis of water-soluble fluorescent gold nanoclusters for sensitive and selective detection of Ag+".journal of materials chemistry c 1.5(2013):908-913. |
入库方式: OAI收割
来源:长春应用化学研究所
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