Facile synthesis of a Co3O4-carbon nanotube composite and its superior performance as an anode material for Li-ion batteries
文献类型：期刊论文
| 作者 | Zhuo LH ; Wu YQ ; Ming J ; Wang LY ; Yu YC ; Zhang XB ; Zhao FY |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2013 |
| 卷号 | 1期号:4页码:1141-1147 |
| 关键词 | IMPROVED REVERSIBLE CAPACITY WALLED CARBON NANOTUBES LITHIUM STORAGE COAXIAL NANOCABLES ELECTROCHEMICAL PERFORMANCE ELECTRODE MATERIALS NANOCOMPOSITES STABILITY HYBRID OXIDE |
| ISSN号 | 2050-7488 |
| 通讯作者 | zhuo lh |
| 中文摘要 | in this work, we report a facile method for the synthesis of a co3o4-functionalized carbon nanotube (co3o4-f-cnt) composite via the growth of co3o4 nanoparticles on the surface of functionalized carbon nanotubes (f-cnts) by thermal decomposition of cobalt nitrate hexahydrate in ethanol. the composite consists of 13% carbon nanotubes and 87% co3o4 nanoparticles by weight, and all the co3o4 particles grew compactly along the carbon nanotube axis with a highly uniform dispersion. when used as an anode material for rechargeable lithium ion batteries, the composite manifested high capacities and excellent cycling performance at high and low current rates. the discharge capacity was 719 ma h g(-1) at the 2nd cycle and 776 ma h g(-1) at the 100th cycle. even at a current density of 1 a g(-1), the specific capacity still remained at about 600 ma h g(-1). this superior electrochemical performance was attributed to the unique nanostructure of the composite. because almost all of the co3o4 nanoparticles were immobilized on the surface of f-cnts, physical aggregation of nanoparticles was avoided during the charge-discharge processes. furthermore, the good mechanical flexibility of f-cnts can readily alleviate the massive volume expansion/shrinkage associated with a conversion reaction electrode. finally, f-cnts are highly conductive matrices for electrons due to their high conductivity, which can shorten the diffusion path for electrons. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000314633500023 |
| 公开日期 | 2014-04-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50385]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhuo LH,Wu YQ,Ming J,et al. Facile synthesis of a Co3O4-carbon nanotube composite and its superior performance as an anode material for Li-ion batteries[J]. journal of materials chemistry a,2013,1(4):1141-1147. |
| APA | Zhuo LH.,Wu YQ.,Ming J.,Wang LY.,Yu YC.,...&Zhao FY.(2013).Facile synthesis of a Co3O4-carbon nanotube composite and its superior performance as an anode material for Li-ion batteries.journal of materials chemistry a,1(4),1141-1147. |
| MLA | Zhuo LH,et al."Facile synthesis of a Co3O4-carbon nanotube composite and its superior performance as an anode material for Li-ion batteries".journal of materials chemistry a 1.4(2013):1141-1147. |
入库方式： OAI收割
来源：长春应用化学研究所
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