Self-assembly structures of amphiphilic multiblock copolymer in dilute solution
文献类型：期刊论文
| 作者 | Zhang J ; Lu ZY ; Sun ZY |
| 刊名 | soft matter
 |
| 出版日期 | 2013 |
| 卷号 | 9期号:6页码:1947-1954 |
| 关键词 | UNIMOLECULAR-MICELLE FORMATION POLY(METHYL METHACRYLATE)-GRAFT-POLYSTYRENE ASSOCIATING POLYMERS BLOCK-COPOLYMERS DRUG-DELIVERY AQUEOUS-MEDIA SIMULATIONS DYNAMICS SOLVENT CHAIN |
| ISSN号 | 1744-683x |
| 通讯作者 | lu zy |
| 中文摘要 | we study the influence of solvent conditions and the chain backbone stiffness of an amphiphilic multiblock copolymer on its self-assembly structures in dilute solution with brownian dynamics simulations. various interesting structures, such as single-flower micelle, multi-flower micelle, and single or multi-bridge structures, are observed. in general, highly hydrophobic components benefit the formation of flower micelle structures, while semi-flexible chains are prone to forming bridge structures. we also study the influence of the ratio between hydrophobic and hydrophilic components on self-assembly structures. from our phase diagram, we find that a high component ratio for the hydrophobic blocks favors the formation of micelles with various structural patterns. a single to multi-flower transition is observed by increasing the chain length of the multiblock copolymer. well-defined multicompartment wormlike micelles can be obtained from pre-assembled flower micelles in a solvent that is poor for both components. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000313594200025 |
| 公开日期 | 2014-04-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50404]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang J,Lu ZY,Sun ZY. Self-assembly structures of amphiphilic multiblock copolymer in dilute solution[J]. soft matter,2013,9(6):1947-1954. |
| APA | Zhang J,Lu ZY,&Sun ZY.(2013).Self-assembly structures of amphiphilic multiblock copolymer in dilute solution.soft matter,9(6),1947-1954. |
| MLA | Zhang J,et al."Self-assembly structures of amphiphilic multiblock copolymer in dilute solution".soft matter 9.6(2013):1947-1954. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。