Synthesis and photoluminescence properties of Ce3+ and Eu2+-activated Ca7Mg(SiO4)(4) phosphors for solid state lighting
文献类型:期刊论文
作者 | Jia YC ; Qiao H ; Zheng YH ; Guo N ; You HP |
刊名 | physical chemistry chemical physics
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出版日期 | 2012 |
卷号 | 14期号:10页码:3537-3542 |
关键词 | EMITTING-DIODES YELLOW PHOSPHOR ENERGY-TRANSFER WHITE LEDS LUMINESCENCE BREDIGITE EU2+ FLUORESCENCE SILICATES LI2SRSIO4 |
ISSN号 | 1463-9076 |
通讯作者 | you hp |
中文摘要 | ce3+ and eu2+ singly doped and ce3+/eu2+-codoped ca7mg(sio4)(4) phosphors are synthesized by the conventional solid state reaction. the ce3+ activated sample exhibits intense blue emission under 350 nm excitation, the composition-optimized ca7mg(sio4)(4):4% ce3+ shows better color purity than the commercial blue phosphor, bamgal10o17:eu2+ (bam:eu2+) and exhibits superior external quantum efficiency (65%). the ca7mg(sio4)4:eu2+ powder shows a broad emission band in the wavelength range of 400-600 nm with a maximum at about 500 nm. the strong excitation bands of the ca7mg(sio4)(4):eu2+ in the wavelength range of 250-450 nm are favorable properties for applications as light-emitting-diode conversion phosphors. furthermore, the energy transfer from the ce3+ to eu2+ ions is observed in the codoped samples, the resonance-type energy transfer is determined to be due to the dipole-dipole interaction mechanism and the critical distance is obtained through the spectral overlap approach and concentration quenching method. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000300314100032 |
公开日期 | 2014-04-18 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50447] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Jia YC,Qiao H,Zheng YH,et al. Synthesis and photoluminescence properties of Ce3+ and Eu2+-activated Ca7Mg(SiO4)(4) phosphors for solid state lighting[J]. physical chemistry chemical physics,2012,14(10):3537-3542. |
APA | Jia YC,Qiao H,Zheng YH,Guo N,&You HP.(2012).Synthesis and photoluminescence properties of Ce3+ and Eu2+-activated Ca7Mg(SiO4)(4) phosphors for solid state lighting.physical chemistry chemical physics,14(10),3537-3542. |
MLA | Jia YC,et al."Synthesis and photoluminescence properties of Ce3+ and Eu2+-activated Ca7Mg(SiO4)(4) phosphors for solid state lighting".physical chemistry chemical physics 14.10(2012):3537-3542. |
入库方式: OAI收割
来源:长春应用化学研究所
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