New polyoxometalate-based mononuclear lanthanide complexes with slow relaxation of magnetization
文献类型：期刊论文
| 作者 | Zhou WZ ; Feng XJ ; Ke HS ; Li YG ; Tang JK ; Wang EB |
| 刊名 | inorganica chimica acta
 |
| 出版日期 | 2013 |
| 卷号 | 394页码:770-775 |
| 关键词 | SINGLE-MOLECULE-MAGNET METAL-ORGANIC FRAMEWORKS LIGAND-FIELD PARAMETERS ION MAGNET COORDINATION BEHAVIOR SPECTROSCOPY BARRIER STATES LEVEL |
| ISSN号 | 0020-1693 |
| 通讯作者 | li yg |
| 中文摘要 | a series of new polyoxometalate(pom)-based mononuclear lanthanide(iii)-bi pyridine-n-oxide complexes, [ln(bpyno)(4)][pmo12o40]center dot 2h(2)o (ln = dy (1), tb (2), er (3), ho (4); bpyno = 4,4'-dimethyl-2,2'-bipyridyl-n-n'-dioxide), have been synthesized by the reactions between lnpmo(12)o(40) salts (ln = dy (1), tb (2), er (3), ho (4)) and bpyno ligand. all compounds were characterized by elemental analyses, tg analyses, ir, powder x-ray diffraction and single-crystal x-ray diffraction. in 1-4, each mononuclear ln center is coordinated by eight o atoms derived from four bpyno ligands, exhibiting an approximate square antiprismatic coordination geometry. furthermore, the [ln(bpyno)(4)](3+) units are well separated by the alpha-keggin-type polyoxoanions. magnetic measurements indicate that compound 1 exhibits frequency dependent ac magnetic susceptibilities indicative of slow relaxation of the magnetization. (c) 2012 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000311492900102 |
| 公开日期 | 2014-04-20 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/50467]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhou WZ,Feng XJ,Ke HS,et al. New polyoxometalate-based mononuclear lanthanide complexes with slow relaxation of magnetization[J]. inorganica chimica acta,2013,394:770-775. |
| APA | Zhou WZ,Feng XJ,Ke HS,Li YG,Tang JK,&Wang EB.(2013).New polyoxometalate-based mononuclear lanthanide complexes with slow relaxation of magnetization.inorganica chimica acta,394,770-775. |
| MLA | Zhou WZ,et al."New polyoxometalate-based mononuclear lanthanide complexes with slow relaxation of magnetization".inorganica chimica acta 394(2013):770-775. |
入库方式： OAI收割
来源：长春应用化学研究所
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