中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries

文献类型:期刊论文

作者Guo LM ; Peng ZQ
刊名chinese journal of analytical chemistry
出版日期2013
卷号41期号:2页码:307-314
关键词TEMPERATURE IONIC LIQUIDS SUPEROXIDE ION REDUCTION LITHIUM ELECTROCHEMISTRY ELECTROREDUCTION SOLVENTS MEDIA
ISSN号0253-3820
通讯作者peng zq
中文摘要li-air batteries utilizing li-o-2 reactions have the highest theoretical capacity and energy density in the li-battery family, and potentially have the ability to transform energy storage. thus, it is crucial to understand the oxygen reaction mechanism in li+ electrolyte because it is the core reaction occurring in the li-air cells currently under intense r&d. this review summarized the oxygen reaction mechanism during discharge and charge of a nonaqueous li-air cell by taking au/ch3cn as a model system: on discharge, o-2 is reduced to o-2(-), which then forms lio2 on the electrode surface which disproportionates to li2o2. on charging, li2o2 decomposes directly, in a one-step reaction to evolve o-2 and does not pass through lio2 as an intermediate. along with presenting the oxygen reaction mechanism, the relevant electrochemical methods are also described.
收录类别SCI收录期刊论文
语种中文
WOS记录号WOS:000318392300026
公开日期2014-04-20
源URL[http://ir.ciac.jl.cn/handle/322003/50495]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Guo LM,Peng ZQ. Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries[J]. chinese journal of analytical chemistry,2013,41(2):307-314.
APA Guo LM,&Peng ZQ.(2013).Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries.chinese journal of analytical chemistry,41(2),307-314.
MLA Guo LM,et al."Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries".chinese journal of analytical chemistry 41.2(2013):307-314.

入库方式: OAI收割

来源:长春应用化学研究所

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