Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries
文献类型:期刊论文
作者 | Guo LM ; Peng ZQ |
刊名 | chinese journal of analytical chemistry
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出版日期 | 2013 |
卷号 | 41期号:2页码:307-314 |
关键词 | TEMPERATURE IONIC LIQUIDS SUPEROXIDE ION REDUCTION LITHIUM ELECTROCHEMISTRY ELECTROREDUCTION SOLVENTS MEDIA |
ISSN号 | 0253-3820 |
通讯作者 | peng zq |
中文摘要 | li-air batteries utilizing li-o-2 reactions have the highest theoretical capacity and energy density in the li-battery family, and potentially have the ability to transform energy storage. thus, it is crucial to understand the oxygen reaction mechanism in li+ electrolyte because it is the core reaction occurring in the li-air cells currently under intense r&d. this review summarized the oxygen reaction mechanism during discharge and charge of a nonaqueous li-air cell by taking au/ch3cn as a model system: on discharge, o-2 is reduced to o-2(-), which then forms lio2 on the electrode surface which disproportionates to li2o2. on charging, li2o2 decomposes directly, in a one-step reaction to evolve o-2 and does not pass through lio2 as an intermediate. along with presenting the oxygen reaction mechanism, the relevant electrochemical methods are also described. |
收录类别 | SCI收录期刊论文 |
语种 | 中文 |
WOS记录号 | WOS:000318392300026 |
公开日期 | 2014-04-20 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50495] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Guo LM,Peng ZQ. Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries[J]. chinese journal of analytical chemistry,2013,41(2):307-314. |
APA | Guo LM,&Peng ZQ.(2013).Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries.chinese journal of analytical chemistry,41(2),307-314. |
MLA | Guo LM,et al."Oxygen Electrode Reactions in Nonaqueous Li-Air Batteries".chinese journal of analytical chemistry 41.2(2013):307-314. |
入库方式: OAI收割
来源:长春应用化学研究所
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