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alpha-Fe2O3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention
文献类型：期刊论文
| 作者 | Xu, Simeng1; Hessel, Colin M.2; Ren, Hao1; Yu, Ranbo1; Jin, Quan2; Yang, Mei2; Zhao, Huijun3; Wang, Dan2 |
| 刊名 | ENERGY & ENVIRONMENTAL SCIENCE
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 7期号:2页码:632-637 |
| 关键词 | negative-electrode storage properties nanostructured materials energy-conversion accurate control metal-oxide spheres performance nanotubes devices |
| ISSN号 | 1754-5692 |
| 其他题名 | Energy Environ. Sci. |
| 中文摘要 | Multi-shelled alpha-Fe2O3 hollow microspheres were synthesized using carbonaceous microsphere sacrificial templates and utilized for high capacity anode materials in lithium ion batteries (LIBs). Structural aspects including the shell thickness, number of internal multi-shells, and shell porosity were controlled by synthesis parameters to produce hollow microspheres with maximum lithium capacity and stable cycling behavior. Thin, porous, hollow microspheres with three concentric multi-shells showed the best cycling performance, demonstrating excellent stability and a reversible capacity of up to 1702 mA h g(-1) at a current density of 50 mA g(-1). The electrode performance is attributed to the large specific surface area and enhanced volumetric capacity of the multi-shelled hollow spheres that provide maximum lithium storage, while the porous thin shells facilitate rapid electrochemical kinetics and buffer mechanical stresses that accompany volume changes during de/lithiation. |
| 英文摘要 | Multi-shelled alpha-Fe2O3 hollow microspheres were synthesized using carbonaceous microsphere sacrificial templates and utilized for high capacity anode materials in lithium ion batteries (LIBs). Structural aspects including the shell thickness, number of internal multi-shells, and shell porosity were controlled by synthesis parameters to produce hollow microspheres with maximum lithium capacity and stable cycling behavior. Thin, porous, hollow microspheres with three concentric multi-shells showed the best cycling performance, demonstrating excellent stability and a reversible capacity of up to 1702 mA h g(-1) at a current density of 50 mA g(-1). The electrode performance is attributed to the large specific surface area and enhanced volumetric capacity of the multi-shelled hollow spheres that provide maximum lithium storage, while the porous thin shells facilitate rapid electrochemical kinetics and buffer mechanical stresses that accompany volume changes during de/lithiation. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology ; Life Sciences & Biomedicine |
| 类目[WOS] | Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
| 关键词[WOS] | NEGATIVE-ELECTRODE ; STORAGE PROPERTIES ; NANOSTRUCTURED MATERIALS ; ENERGY-CONVERSION ; ACCURATE CONTROL ; METAL-OXIDE ; SPHERES ; PERFORMANCE ; NANOTUBES ; DEVICES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000331413700012 |
| 公开日期 | 2014-05-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/8026]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Univ Sci & Technol Beijing, Dept Phys Chem, Sch Met & Ecol Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 3.Griffith Univ, Ctr Clean Environm & Energy, Brisbane, Qld 4222, Australia |
| 推荐引用方式 GB/T 7714 | Xu, Simeng,Hessel, Colin M.,Ren, Hao,et al. alpha-Fe2O3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention[J]. ENERGY & ENVIRONMENTAL SCIENCE,2014,7(2):632-637. |
| APA | Xu, Simeng.,Hessel, Colin M..,Ren, Hao.,Yu, Ranbo.,Jin, Quan.,...&Wang, Dan.(2014).alpha-Fe2O3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention.ENERGY & ENVIRONMENTAL SCIENCE,7(2),632-637. |
| MLA | Xu, Simeng,et al."alpha-Fe2O3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention".ENERGY & ENVIRONMENTAL SCIENCE 7.2(2014):632-637. |
入库方式： OAI收割
来源：过程工程研究所
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