Artificial photosynthesis for solar hydrogen generation over transition-metal substituted Keggin-type titanium tungstate
文献类型：期刊论文
| 作者 | Shang, Xinke1,2; Liu, Rongji1,2; Zhang, Guangjin1; Zhang, Suojiang1; Cao, Hongbin1; Gu, Zhanjun3 |
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 38期号:3页码:1315-1320 |
| 关键词 | visible-light irradiation water heteropolytungstates photocatalysts lanthanide reduction catalysis natao3 cells |
| ISSN号 | 1144-0546 |
| 其他题名 | New J. Chem. |
| 中文摘要 | The photocatalytic hydrogen (H-2) evolution with transition-metal substituted Keggin-type titanium tungstates Na-5(6)[MTiW11O39]center dot xH(2)O (abbreviated as TiW11M (M = Fe, Co, Zn)) as photocatalyst was reported. They showed good photocatalytic activities toward H-2 evolution in homogeneous systems under simulated solar light irradiation. The order of photocatalytic activity was TiW11Co approximate to TiW11Zn > TiW11Fe >> H3PW12O40 (PW12). The selected POMs showed good stability during the reactions. Karl Fischer analysis, ICPE (Inductive Coupled Plasma Emission) and FT-IR (Fourier Transform Infrared Spectroscopy) were used to confirm the composition and structure. UV-Vis absorption spectra, kinetics investigation and cyclic voltammetric characterizations were used to explain the photocatalytic results. Finally, an analogous "Z-scheme'' mechanism was proposed for the homogeneous systems toward photocatalytic H-2 evolution under simulated solar light irradiation. |
| 英文摘要 | The photocatalytic hydrogen (H-2) evolution with transition-metal substituted Keggin-type titanium tungstates Na-5(6)[MTiW11O39]center dot xH(2)O (abbreviated as TiW11M (M = Fe, Co, Zn)) as photocatalyst was reported. They showed good photocatalytic activities toward H-2 evolution in homogeneous systems under simulated solar light irradiation. The order of photocatalytic activity was TiW11Co approximate to TiW11Zn > TiW11Fe >> H3PW12O40 (PW12). The selected POMs showed good stability during the reactions. Karl Fischer analysis, ICPE (Inductive Coupled Plasma Emission) and FT-IR (Fourier Transform Infrared Spectroscopy) were used to confirm the composition and structure. UV-Vis absorption spectra, kinetics investigation and cyclic voltammetric characterizations were used to explain the photocatalytic results. Finally, an analogous "Z-scheme'' mechanism was proposed for the homogeneous systems toward photocatalytic H-2 evolution under simulated solar light irradiation. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | VISIBLE-LIGHT IRRADIATION ; WATER ; HETEROPOLYTUNGSTATES ; PHOTOCATALYSTS ; LANTHANIDE ; REDUCTION ; CATALYSIS ; NATAO3 ; CELLS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000331805000057 |
| 公开日期 | 2014-05-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/8031]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shang, Xinke,Liu, Rongji,Zhang, Guangjin,et al. Artificial photosynthesis for solar hydrogen generation over transition-metal substituted Keggin-type titanium tungstate[J]. NEW JOURNAL OF CHEMISTRY,2014,38(3):1315-1320. |
| APA | Shang, Xinke,Liu, Rongji,Zhang, Guangjin,Zhang, Suojiang,Cao, Hongbin,&Gu, Zhanjun.(2014).Artificial photosynthesis for solar hydrogen generation over transition-metal substituted Keggin-type titanium tungstate.NEW JOURNAL OF CHEMISTRY,38(3),1315-1320. |
| MLA | Shang, Xinke,et al."Artificial photosynthesis for solar hydrogen generation over transition-metal substituted Keggin-type titanium tungstate".NEW JOURNAL OF CHEMISTRY 38.3(2014):1315-1320. |
入库方式： OAI收割
来源：过程工程研究所
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