Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids
文献类型：期刊论文
| 作者 | Wang, Jin-Quan; Cheng, Wei-Guo; Sun, Jian; Shi, Tian-Yuan; Zhang, Xiang-Ping; Zhang, Suo-Jiang |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:5页码:2360-2367 |
| 关键词 | cyclic carbonate dimethyl carbonate highly efficient propylene-oxide ethylene-oxide dioxide epoxides cycloaddition transformation conversion |
| ISSN号 | 2046-2069 |
| 其他题名 | RSC Adv. |
| 中文摘要 | Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbonates from CO2 and epoxides without the use of any co-catalysts or organic solvent. Moreover, the 2-hydroxymethyl-functionalized ILs were compatible with base, which combined with K2CO3 were used as effective catalytic system for green synthesis of dimethyl carbonate from CO2 via ethylene carbonate without catalyst separation. Additionally, the mechanistic details of the fixation of CO2 into cyclic carbonate catalyzed by 2-hydroxymethyl-functionalized ILs were also elucidated by density functional theory. The process reported here represents a simple, ecologically safer, cost-effective and energy-saving route to organic carbonates from CO2. |
| 英文摘要 | Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbonates from CO2 and epoxides without the use of any co-catalysts or organic solvent. Moreover, the 2-hydroxymethyl-functionalized ILs were compatible with base, which combined with K2CO3 were used as effective catalytic system for green synthesis of dimethyl carbonate from CO2 via ethylene carbonate without catalyst separation. Additionally, the mechanistic details of the fixation of CO2 into cyclic carbonate catalyzed by 2-hydroxymethyl-functionalized ILs were also elucidated by density functional theory. The process reported here represents a simple, ecologically safer, cost-effective and energy-saving route to organic carbonates from CO2. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CYCLIC CARBONATE ; DIMETHYL CARBONATE ; HIGHLY EFFICIENT ; PROPYLENE-OXIDE ; ETHYLENE-OXIDE ; DIOXIDE ; EPOXIDES ; CYCLOADDITION ; TRANSFORMATION ; CONVERSION |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000329035400038 |
| 公开日期 | 2014-05-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/8087]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jin-Quan,Cheng, Wei-Guo,Sun, Jian,et al. Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids[J]. RSC ADVANCES,2014,4(5):2360-2367. |
| APA | Wang, Jin-Quan,Cheng, Wei-Guo,Sun, Jian,Shi, Tian-Yuan,Zhang, Xiang-Ping,&Zhang, Suo-Jiang.(2014).Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids.RSC ADVANCES,4(5),2360-2367. |
| MLA | Wang, Jin-Quan,et al."Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids".RSC ADVANCES 4.5(2014):2360-2367. |
入库方式： OAI收割
来源：过程工程研究所
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