Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids
文献类型：期刊论文
| 作者 | Chen, Shimou1; Zhang, Suojiang1; Liu, Xiaomin1; Wang, Jinquan1; Wang, Jianji2; Dong, Kun1; Sun, Jian1; Xu, Baohua1 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:13页码:5893-5906 |
| 关键词 | ray photoelectron-spectroscopy molecular-dynamics simulations silica-derived networks alkyl chain-length room-temperature aqueous-solution micelle formation aggregation behavior nanostructural organization physicochemical properties |
| ISSN号 | 1463-9076 |
| 其他题名 | Phys. Chem. Chem. Phys. |
| 中文摘要 | The microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in physiochemical properties and behavior of ILs. The existence of clusters (or microheterogeneous structure) is one of the main features for many ILs, which provides fundamental information for understanding the performance of ILs in their applications. This perspective concentrates on the recent progresses in IL clusters research. Firstly, we give a brief introduction on the structure of clusters in neat ILs and IL solutions. Secondly, the possible formation mechanism of the IL clusters is described. Then, the effects of the clusters on the physicochemical properties, interfacial properties, confined geometry and assembly processes of ILs are discussed. Finally, we address the associated challenges and prospects on the future study of IL clusters. |
| 英文摘要 | The microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in physiochemical properties and behavior of ILs. The existence of clusters (or microheterogeneous structure) is one of the main features for many ILs, which provides fundamental information for understanding the performance of ILs in their applications. This perspective concentrates on the recent progresses in IL clusters research. Firstly, we give a brief introduction on the structure of clusters in neat ILs and IL solutions. Secondly, the possible formation mechanism of the IL clusters is described. Then, the effects of the clusters on the physicochemical properties, interfacial properties, confined geometry and assembly processes of ILs are discussed. Finally, we address the associated challenges and prospects on the future study of IL clusters. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | RAY PHOTOELECTRON-SPECTROSCOPY ; MOLECULAR-DYNAMICS SIMULATIONS ; SILICA-DERIVED NETWORKS ; ALKYL CHAIN-LENGTH ; ROOM-TEMPERATURE ; AQUEOUS-SOLUTION ; MICELLE FORMATION ; AGGREGATION BEHAVIOR ; NANOSTRUCTURAL ORGANIZATION ; PHYSICOCHEMICAL PROPERTIES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000332474700001 |
| 公开日期 | 2014-05-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/8132]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 2.Henan Normal Univ, Minist Educ, Key Lab Green Chem Media & React, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Shimou,Zhang, Suojiang,Liu, Xiaomin,et al. Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2014,16(13):5893-5906. |
| APA | Chen, Shimou.,Zhang, Suojiang.,Liu, Xiaomin.,Wang, Jinquan.,Wang, Jianji.,...&Xu, Baohua.(2014).Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,16(13),5893-5906. |
| MLA | Chen, Shimou,et al."Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 16.13(2014):5893-5906. |
入库方式： OAI收割
来源：过程工程研究所
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