Multiple transition metal oxide mesoporous nanospheres with controllable composition for lithium storage
文献类型：期刊论文
| 作者 | Zhang, Zailei; Tan, Qiangqiang; Chen, Yunfa; Yang, Jun; Su, Fabing |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2014 |
| 卷号 | 2期号:14页码:5041-5050 |
| 关键词 | li-ion batteries enhanced catalytic performance oxygen reduction reaction dimethyldichlorosilane synthesis supercapacitor electrodes nanocrystal synthesis nanoporous carbon cuo microspheres general strategy facile synthesis |
| ISSN号 | 2050-7488 |
| 其他题名 | J. Mater. Chem. A |
| 中文摘要 | A general synthetic method based on a solvothermal route for the preparation of multiple transition metal oxide (MTMO) mesoporous nanospheres (ZnaNibMncCodFe2O4, 0 <= a, b, c, d <= 1, a + b + c + d = 1) with controllable composition and uniform size distribution has been developed. The as-prepared ZnaNibMncCodFe2O4 nanospheres are formed by self-assembly of nanocrystals with the size of 5-10 nm via structure-directing agents and mineralizer coordinating effect as well as optimization of the synthesis conditions. It has been identified that the addition of mineralizer is crucial for the control of the nucleation process when the metallic precursors are reduced; meanwhile the structure-directing agent is key to forming the mesoporous structure. A number of characterization techniques including X-ray diffraction, transmission electron microscopy, scanning electron microscopy, inductively coupled plasma optical emission spectrometry, temperature-programmed reduction, and nitrogen adsorption have been used to characterize the as-prepared mesoporous products. The overall strategy in this work extends the controllable fabrication of high-quality MTMO mesoporous nanospheres with designed components and compositions, rendering these nanospheres with promising potential for various applications (oxygen reduction reaction, magnetic performance, supercapacitor, lithium-ion batteries, and catalysis). |
| 英文摘要 | A general synthetic method based on a solvothermal route for the preparation of multiple transition metal oxide (MTMO) mesoporous nanospheres (ZnaNibMncCodFe2O4, 0 <= a, b, c, d <= 1, a + b + c + d = 1) with controllable composition and uniform size distribution has been developed. The as-prepared ZnaNibMncCodFe2O4 nanospheres are formed by self-assembly of nanocrystals with the size of 5-10 nm via structure-directing agents and mineralizer coordinating effect as well as optimization of the synthesis conditions. It has been identified that the addition of mineralizer is crucial for the control of the nucleation process when the metallic precursors are reduced; meanwhile the structure-directing agent is key to forming the mesoporous structure. A number of characterization techniques including X-ray diffraction, transmission electron microscopy, scanning electron microscopy, inductively coupled plasma optical emission spectrometry, temperature-programmed reduction, and nitrogen adsorption have been used to characterize the as-prepared mesoporous products. The overall strategy in this work extends the controllable fabrication of high-quality MTMO mesoporous nanospheres with designed components and compositions, rendering these nanospheres with promising potential for various applications (oxygen reduction reaction, magnetic performance, supercapacitor, lithium-ion batteries, and catalysis). |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | LI-ION BATTERIES ; ENHANCED CATALYTIC PERFORMANCE ; OXYGEN REDUCTION REACTION ; DIMETHYLDICHLOROSILANE SYNTHESIS ; SUPERCAPACITOR ELECTRODES ; NANOCRYSTAL SYNTHESIS ; NANOPOROUS CARBON ; CUO MICROSPHERES ; GENERAL STRATEGY ; FACILE SYNTHESIS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000332935300028 |
| 公开日期 | 2014-05-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/8144]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zailei,Tan, Qiangqiang,Chen, Yunfa,et al. Multiple transition metal oxide mesoporous nanospheres with controllable composition for lithium storage[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(14):5041-5050. |
| APA | Zhang, Zailei,Tan, Qiangqiang,Chen, Yunfa,Yang, Jun,&Su, Fabing.(2014).Multiple transition metal oxide mesoporous nanospheres with controllable composition for lithium storage.JOURNAL OF MATERIALS CHEMISTRY A,2(14),5041-5050. |
| MLA | Zhang, Zailei,et al."Multiple transition metal oxide mesoporous nanospheres with controllable composition for lithium storage".JOURNAL OF MATERIALS CHEMISTRY A 2.14(2014):5041-5050. |
入库方式： OAI收割
来源：过程工程研究所
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