Promoting effect of nitration modification on activated carbon in the catalytic ozonation of oxalic acid
文献类型：期刊论文
| 作者 | Cao, Hongbin1,2,3; Xing, Linlin1,2,3; Wu, Guangguo1,2,3; Xie, Yongbing1,2,3; Shi, Shaoyuan1,2,3; Zhang, Yi1,2,3; Minakata, Daisuke4; Crittenden, John C.4 |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2014-03-01 |
| 卷号 | 146期号:1页码:169-176 |
| 关键词 | Catalytic ozonation Activated carbon Surface modification Nitration Amination |
| ISSN号 | 0926-3373 |
| 其他题名 | Appl. Catal. B-Environ. |
| 中文摘要 | A commercial activated carbon (AC) was modified with a nitration or amination method, and the effects of textural and chemical properties on the ability of the AC samples to destroy oxalic acid (OA) using ozone was investigated in this work. The degradation rates of OA on the nitrated and aminated AC samples increased by 38.5% and 9.6%, respectively. The adsorption capacity of the AC sample was not enhanced after modification, but the decomposition rate of ozone in solution increased. The surface area of AC significantly decreased after nitration because the entrance of micropores and some larger pores were blocked by the modified functional groups. In addition, the surface area was recovered when the nitrated AC was further aminated. We demonstrated that the enhancement in the catalytic activity was primarily caused by the differences in surface chemistry. The pH(pzc) values and Boehm titration results showed that nitration increased the acidity of the AC, while more basic groups were grafted after amination. X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD) results confirmed that-NO2 and acid oxygenated groups were simultaneously grafted onto AC during nitration. Meanwhile, the-NO2 group was completely reduced to-NH2 and the carboxylic groups were partially reduced during amination. The basic groups (-NH2 and possible pyrone groups) enhanced the catalytic activity of the aminated AC sample, and the increased activity of the nitrated AC material was mainly due to the acid oxygenated surface groups. (C) 2013 Elsevier B.V. All rights reserved. |
| 英文摘要 | A commercial activated carbon (AC) was modified with a nitration or amination method, and the effects of textural and chemical properties on the ability of the AC samples to destroy oxalic acid (OA) using ozone was investigated in this work. The degradation rates of OA on the nitrated and aminated AC samples increased by 38.5% and 9.6%, respectively. The adsorption capacity of the AC sample was not enhanced after modification, but the decomposition rate of ozone in solution increased. The surface area of AC significantly decreased after nitration because the entrance of micropores and some larger pores were blocked by the modified functional groups. In addition, the surface area was recovered when the nitrated AC was further aminated. We demonstrated that the enhancement in the catalytic activity was primarily caused by the differences in surface chemistry. The pH(pzc) values and Boehm titration results showed that nitration increased the acidity of the AC, while more basic groups were grafted after amination. X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD) results confirmed that-NO2 and acid oxygenated groups were simultaneously grafted onto AC during nitration. Meanwhile, the-NO2 group was completely reduced to-NH2 and the carboxylic groups were partially reduced during amination. The basic groups (-NH2 and possible pyrone groups) enhanced the catalytic activity of the aminated AC sample, and the increased activity of the nitrated AC material was mainly due to the acid oxygenated surface groups. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | OZONE/ACTIVATED CARBON ; OZONE DECOMPOSITION ; SURFACE-CHEMISTRY ; ORGANIC-COMPOUNDS ; AQUEOUS-SOLUTIONS ; WATER-TREATMENT ; RATE CONSTANTS ; ADSORPTION ; TEMPERATURE ; EFFICIENCY |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000327904000020 |
| 公开日期 | 2014-05-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/8179]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Res Ctr Proc Pollut Control, Inst Proc Engn, Beijing 100190, Peoples R China 3.Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 4.Georgia Inst Technol, Brook Byers Inst Sustainable Syst, Atlanta, GA 30332 USA |
| 推荐引用方式 GB/T 7714 | Cao, Hongbin,Xing, Linlin,Wu, Guangguo,et al. Promoting effect of nitration modification on activated carbon in the catalytic ozonation of oxalic acid[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2014,146(1):169-176. |
| APA | Cao, Hongbin.,Xing, Linlin.,Wu, Guangguo.,Xie, Yongbing.,Shi, Shaoyuan.,...&Crittenden, John C..(2014).Promoting effect of nitration modification on activated carbon in the catalytic ozonation of oxalic acid.APPLIED CATALYSIS B-ENVIRONMENTAL,146(1),169-176. |
| MLA | Cao, Hongbin,et al."Promoting effect of nitration modification on activated carbon in the catalytic ozonation of oxalic acid".APPLIED CATALYSIS B-ENVIRONMENTAL 146.1(2014):169-176. |
入库方式： OAI收割
来源：过程工程研究所
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