Oxidative steam reforming of ethanol over Rh catalyst supported on Ce1-xLaxOy (x=0.3) solid solution prepared by urea co-precipitation method
文献类型：期刊论文
| 作者 | Han, Xue ; Yu, Yunbo ; He, Hong ; Zhao, Jiaojiao ; Wang, Yafei |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2013 |
| 卷号 | 238页码:57-64 |
| 通讯作者 | Yu, YB |
| 中文摘要 | A Ce1-xLaxOy solid solution (CL) is prepared by a co-precipitation method using urea as a precipitant, with varying urea/metal molar ratio (N). The supported rhodium catalysts are then prepared by an impregnation method for use in hydrogen production from oxidative steam reforming (OSR) of ethanol. X-ray diffraction and Raman spectra results confirm the formation of CL, and the crystal structures of these catalysts are not very sensitive to the urea/metal molar ratios (N = 5-15). However, the surface area and reducibility of the Rh/CL-N catalysts decrease monotonically with increasing N. During the OSR process, a similar tendency is also observed for ethanol conversion and hydrogen selectivity. Among the catalysts tested, Rh/CL-5 shows the best catalytic performance, achieving >97% ethanol conversion at 300 degrees C with H-2 yield rate of 210 mu mol g-cat(-1) s(-1). At 450 degrees C, its hydrogen selectivity reaches 117%, with no observable change after 72 h aging. (C) 2013 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000320901900008 |
| 公开日期 | 2014-06-04 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/7256]  |
| 专题 | 生态环境研究中心_大气环境科学实验室 |
| 推荐引用方式 GB/T 7714 | Han, Xue,Yu, Yunbo,He, Hong,et al. Oxidative steam reforming of ethanol over Rh catalyst supported on Ce1-xLaxOy (x=0.3) solid solution prepared by urea co-precipitation method[J]. JOURNAL OF POWER SOURCES,2013,238:57-64. |
| APA | Han, Xue,Yu, Yunbo,He, Hong,Zhao, Jiaojiao,&Wang, Yafei.(2013).Oxidative steam reforming of ethanol over Rh catalyst supported on Ce1-xLaxOy (x=0.3) solid solution prepared by urea co-precipitation method.JOURNAL OF POWER SOURCES,238,57-64. |
| MLA | Han, Xue,et al."Oxidative steam reforming of ethanol over Rh catalyst supported on Ce1-xLaxOy (x=0.3) solid solution prepared by urea co-precipitation method".JOURNAL OF POWER SOURCES 238(2013):57-64. |
入库方式： OAI收割
来源：生态环境研究中心
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