Identification of Tetrabromobisphenol A Allyl Ether and Tetrabromobisphenol A 2,3-Dibromopropyl Ether in the Ambient Environment near a Manufacturing Site and in Mollusks at a Coastal Region
文献类型:期刊论文
作者 | Qu, Guangbo ; Liu, Aifeng ; Thanh Wang ; Zhang, Chaoli ; Fu, Jianjie ; Yu, Miao ; Sun, Jianteng ; Zhu, Nali ; Li, Zhuona ; Wei, Guohua ; Du, Yuguo ; Shi, Jianbo ; Liu, Sijin ; Jiang, Guibin |
刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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出版日期 | 2013 |
卷号 | 47期号:9页码:4760-4767 |
通讯作者 | Shi, JB |
中文摘要 | Tetrabromobisphenol A (TBBPA) is one of the most widely used brominated flame retardants (BFRs) and has been frequently detected in the environment and biota. Recent studies have found that derivatives of TBBPA, such as TBBPA bis(allyl) ether (TBBPA BAE) and TBBPA bis(2,3-dibromopropyl) ether (TBBPA BDBPE) are present in various environmental compartments In this work, using liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS) and liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (LC-QTOF-MS), TBBPA allyl ether (TBBPA AE) and TBBPA 2,3-dibromopropyl ether (TBBPA DBPE) were identified in environmental samples and further confirmed by synthesized standards. Soil, sediment, rice hull, and earthworm samples collected near a BFR manufacturing plant were found to contain these two compounds. In sediments, the concentrations of TBBPA AE and TBBPA DBPE ranged from 1.0 to 3466 ng/g of dry weight (dw) and from 0.7 to 2927 ng/g of dw, respectively. TBBPA AE and TBBPA DBPE in earthworm and rice hull samples were similar to soil samples, which ranged from below the method limit of detection (LOD, <0.002 ng/g of dw) to 0.064 ng/g of dw and from below the LOD (<0.008 ng/g of dw) to 0.58 ng/g of dw, respectively. Furthermore, mollusks collected from the Chinese Bohai Sea were used as a bioindicator to investigate the occurrence and distribution of these compounds in the coastal environment The detection frequencies of TBBPA AE and TBBPA DBPE were 41 and 32%, respectively, and the concentrations ranged from below LOD (<0.003 ng/g of dw) to 0.54 ng/g of dw, with an average of 0.09 ng/g of dw, for TBBPA AE, and from below LOD (<0.008 ng/g of dw) to 1.41 ng/g of dw, with an average of 0.15 ng/g of dw, for TBBPA DBPE. |
收录类别 | SCI |
WOS记录号 | WOS:000318756000101 |
公开日期 | 2014-06-06 |
源URL | [http://ir.rcees.ac.cn/handle/311016/7497] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Qu, Guangbo,Liu, Aifeng,Thanh Wang,et al. Identification of Tetrabromobisphenol A Allyl Ether and Tetrabromobisphenol A 2,3-Dibromopropyl Ether in the Ambient Environment near a Manufacturing Site and in Mollusks at a Coastal Region[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2013,47(9):4760-4767. |
APA | Qu, Guangbo.,Liu, Aifeng.,Thanh Wang.,Zhang, Chaoli.,Fu, Jianjie.,...&Jiang, Guibin.(2013).Identification of Tetrabromobisphenol A Allyl Ether and Tetrabromobisphenol A 2,3-Dibromopropyl Ether in the Ambient Environment near a Manufacturing Site and in Mollusks at a Coastal Region.ENVIRONMENTAL SCIENCE & TECHNOLOGY,47(9),4760-4767. |
MLA | Qu, Guangbo,et al."Identification of Tetrabromobisphenol A Allyl Ether and Tetrabromobisphenol A 2,3-Dibromopropyl Ether in the Ambient Environment near a Manufacturing Site and in Mollusks at a Coastal Region".ENVIRONMENTAL SCIENCE & TECHNOLOGY 47.9(2013):4760-4767. |
入库方式: OAI收割
来源:生态环境研究中心
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