Inhibition mechanism of BrO3- formation over MnOx/Al2O3 during the catalytic ozonation of 2,4-dichlorophenoxyacetic acid in water
文献类型：期刊论文
| 作者 | Nie, Yulun ; Hu, Chun ; Yang, Li ; Hu, Jianchao |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2013 |
| 卷号 | 117期号:1页码:41-45 |
| 通讯作者 | Hu, C |
| 中文摘要 | BrO3- formation from Br- containing drinking water ozonation treatment remains an important challenge. The inhibition mechanism of BrO3- formation was investigated during the catalytic ozonation of 2,4-dichlorophenoxyacetic acid (2,4-D) in mesoporous alumina supported MnOx (MnOx/Al2O3) suspension. The catalyst exhibited both significant inhibition of BrO3- formation and highly efficient catalytic ozonation of 2,4-D. Based on the characterization of UV-Vis spectrum, H2O2 determination and CV analysis, a redox process of bromine species occurred during the oxidation of 2,4-D in catalytic ozonation system. BrO3- reduction to Br- and the reduction of HBrO were responsible for the inhibition of BrO3- formation over MnOx/Al2O3 with ozone. An inhibition mechanism of BrO3- formation was proposed for catalytic ozonation in MnOx/Al2O3 suspension based on all experimental results. These observations will facilitate the development of catalytic ozonation for drinking-water treatment, especially for purification of Br- containing water. Crown Copyright (c) 2013 Published by Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000324604000008 |
| 公开日期 | 2014-06-06 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/7420]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Nie, Yulun,Hu, Chun,Yang, Li,et al. Inhibition mechanism of BrO3- formation over MnOx/Al2O3 during the catalytic ozonation of 2,4-dichlorophenoxyacetic acid in water[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2013,117(1):41-45. |
| APA | Nie, Yulun,Hu, Chun,Yang, Li,&Hu, Jianchao.(2013).Inhibition mechanism of BrO3- formation over MnOx/Al2O3 during the catalytic ozonation of 2,4-dichlorophenoxyacetic acid in water.SEPARATION AND PURIFICATION TECHNOLOGY,117(1),41-45. |
| MLA | Nie, Yulun,et al."Inhibition mechanism of BrO3- formation over MnOx/Al2O3 during the catalytic ozonation of 2,4-dichlorophenoxyacetic acid in water".SEPARATION AND PURIFICATION TECHNOLOGY 117.1(2013):41-45. |
入库方式： OAI收割
来源：生态环境研究中心
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