Sol-gel preparation of efficient red phosphor Mg2TiO4:Mn4+ and XAFS investigation on the substitution of Mn4+ for Ti4+
文献类型:期刊论文
作者 | Ye, Tiannan ; Li, Shan ; Wu, Xueyan ; Xu, Miao ; Wei, Xiao ; Wang, Kaixue ; Bao, Hongliang ; Wang, Jianqiang ; Chen, Jiesheng |
刊名 | JOURNAL OF MATERIALS CHEMISTRY C
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出版日期 | 2013 |
卷号 | 1期号:28页码:CONCATENATE(Sheet1!I309,-Sheet1!J309) |
ISSN号 | 2050-7526 |
英文摘要 | An efficient red phosphor based on the substitution of Mn4+ for Ti4+ in the lattice of Mg2TiO4 was prepared through a sol-gel route. The phosphor was characterized by X-ray diffraction (XRD), electron paramagnetic resonance (EPR) and UV-vis spectroscopy and the luminescent properties of the samples with varying Mn4+ concentrations were investigated. The photoluminescence of the sol-gel prepared Mg2TiO4:Mn4+ phosphor was compared with the corresponding sample prepared via solid-state reaction and the commercial CaAlSiN3:Eu2+. X-ray absorption fine structure (XAFS) investigation reveals the oxidation state and coordination environment of the Mn ion in the crystal structure of Mg2TiO4 and indicates the substitution of Mn4+ for Ti-sites. Moreover, a decrease in lattice parameter was observed with the increase of Mn4+ content in Mg2TiO4, further confirming the replacement of Ti4+ ions by smaller Mn4+ ions in the host lattice. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000321015700004 |
公开日期 | 2014-06-13 |
源URL | [http://ir.sinap.ac.cn/handle/331007/13639] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Ye, Tiannan,Li, Shan,Wu, Xueyan,et al. Sol-gel preparation of efficient red phosphor Mg2TiO4:Mn4+ and XAFS investigation on the substitution of Mn4+ for Ti4+[J]. JOURNAL OF MATERIALS CHEMISTRY C,2013,1(28):CONCATENATE(Sheet1!I309,-Sheet1!J309). |
APA | Ye, Tiannan.,Li, Shan.,Wu, Xueyan.,Xu, Miao.,Wei, Xiao.,...&Chen, Jiesheng.(2013).Sol-gel preparation of efficient red phosphor Mg2TiO4:Mn4+ and XAFS investigation on the substitution of Mn4+ for Ti4+.JOURNAL OF MATERIALS CHEMISTRY C,1(28),CONCATENATE(Sheet1!I309,-Sheet1!J309). |
MLA | Ye, Tiannan,et al."Sol-gel preparation of efficient red phosphor Mg2TiO4:Mn4+ and XAFS investigation on the substitution of Mn4+ for Ti4+".JOURNAL OF MATERIALS CHEMISTRY C 1.28(2013):CONCATENATE(Sheet1!I309,-Sheet1!J309). |
入库方式: OAI收割
来源:上海应用物理研究所
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