Effects of Surface Dipole Lengths on Evaporation of Tiny Water Aggregation
文献类型：期刊论文
| 作者 | Wang Shen(王棽） ; Tu Yu-Song ; Wan Rong-Zheng（万荣正） ; Fang Hai-Ping（方海平） |
| 刊名 | COMMUNICATIONS IN THEORETICAL PHYSICS
 |
| 出版日期 | 2013 |
| 卷号 | 59期号:5页码:CONCATENATE(Sheet1!I105,-Sheet1!J105) |
| ISSN号 | 0253-6102 |
| 英文摘要 | Using molecular dynamics simulation, we compared evaporation behavior of a tiny amount of water molecules adsorbed on solid surfaces with different dipole lengths, including surface dipole lengths of 1 fold, 2 folds, 4 folds, 6 folds and 8 folds of 0.14 nm and different charges from 0.1e to 0.9e. Surfaces with short dipole lengths (1-fold system) can always maintain hydrophobic character and the evaporation speeds are not influenced, whether the surface charges are enhanced or weakened; but when surface dipole lengths get to 8 folds, surfaces become more hydrophilic as the surface charge increases, and the evaporation speeds increase gradually and monotonically. By tuning dipole lengths from 1-fold to 8-fold systems, we confirmed non-monotonic variation of the evaporation flux (first increases, then decreases) in 4 fold system with charges (0.1e-0.7e), reported in our previous paper [S. Wang, et al., J. Phys. Chem. B 116 (2012) 13863], and also show the process from the enhancement of this unexpected non-monotonic variation to its vanishment with surface dipole lengths increasing. Herein, we demonstrated two key factors to influence the evaporation flux of a tiny amount of water molecules adsorbed on solid surfaces: the exposed surficial area of water aggregation from where the water molecules can evaporate directly and the attraction potential from the substrate hindering the evaporation. In addition, more interestingly, we showed extra steric effect of surface dipoles on further increase of evaporation flux for 2-folds, 4-folds, 6-folds and 8-folds systems with charges around larger than 0.7e. (The steric effect is first reported by parts of our authors [C. Wang, et al., Sci. Rep. 2 (2012) 358]). This study presents a complete physical picture of the influence of surface dipole lengths on the evaporation behavior of the adsorbed tiny amount of water. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000319109200017 |
| 公开日期 | 2014-06-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13733]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang Shen,Tu Yu-Song,Wan Rong-Zheng,et al. Effects of Surface Dipole Lengths on Evaporation of Tiny Water Aggregation[J]. COMMUNICATIONS IN THEORETICAL PHYSICS,2013,59(5):CONCATENATE(Sheet1!I105,-Sheet1!J105). |
| APA | Wang Shen,Tu Yu-Song,Wan Rong-Zheng,&Fang Hai-Ping.(2013).Effects of Surface Dipole Lengths on Evaporation of Tiny Water Aggregation.COMMUNICATIONS IN THEORETICAL PHYSICS,59(5),CONCATENATE(Sheet1!I105,-Sheet1!J105). |
| MLA | Wang Shen,et al."Effects of Surface Dipole Lengths on Evaporation of Tiny Water Aggregation".COMMUNICATIONS IN THEORETICAL PHYSICS 59.5(2013):CONCATENATE(Sheet1!I105,-Sheet1!J105). |
入库方式： OAI收割
来源：上海应用物理研究所
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