Electron transfer in N-butylpyridinium tetrafluoroborate ionic liquid by pulse radiolysis
文献类型：期刊论文
| 作者 | Fu HaiYing(付海英） ; Xing ZhaoGuo ; Cao XiYan ; Wu GuoZhong（吴国忠） |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2013 |
| 卷号 | 58期号:16页码:CONCATENATE(Sheet1!I109,-Sheet1!J109) |
| ISSN号 | 1001-6538 |
| 英文摘要 | The radiolysis behavior of neat pyridinium ionic liquids (ILs) and their aqueous solutions was investigated using nanosecond pulse radiolysis techniques. Radiolysis of the ionic liquids, such as N-butylpyridinium tetrafluoroborate (BuPyBF4), resulted in the formation of solvated electrons and organic radicals. Solvated electrons reacted with the pyridinium moiety to produce a pyridinyl radical, which can transfer electrons to various acceptors. The electron-transfer rate constants of the solvent-derived butylpyridinyl radicals in BuPyBF4 and in several compounds (for example, duroquinone, 4,4'-pyridine, benzophenone, and 1,1'-dimethyl-4,4'-bypyridinium dichloride) (k of the order 10(8) L/(mol s) were lower than those measured in water and in i-PrOH but were significantly higher than the diffusion-controlled rate constants estimated based on viscosity. The electron-transfer rate constants in neat BuPyBF4 were one order of magnitude faster than the diffusion-controlled values. This finding suggests that BuPyBF4 acts not only as solvent but also as active solute, such as in solvent-mediated reactions. These reactions result in electrons reaching their final destinations via intervening pyridinium groups without requiring the diffusion of a specific radical. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000319850700007 |
| 公开日期 | 2014-06-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13736]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Fu HaiYing,Xing ZhaoGuo,Cao XiYan,et al. Electron transfer in N-butylpyridinium tetrafluoroborate ionic liquid by pulse radiolysis[J]. CHINESE SCIENCE BULLETIN,2013,58(16):CONCATENATE(Sheet1!I109,-Sheet1!J109). |
| APA | Fu HaiYing,Xing ZhaoGuo,Cao XiYan,&Wu GuoZhong.(2013).Electron transfer in N-butylpyridinium tetrafluoroborate ionic liquid by pulse radiolysis.CHINESE SCIENCE BULLETIN,58(16),CONCATENATE(Sheet1!I109,-Sheet1!J109). |
| MLA | Fu HaiYing,et al."Electron transfer in N-butylpyridinium tetrafluoroborate ionic liquid by pulse radiolysis".CHINESE SCIENCE BULLETIN 58.16(2013):CONCATENATE(Sheet1!I109,-Sheet1!J109). |
入库方式： OAI收割
来源：上海应用物理研究所
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