Facile preparation of polyphenolic hydroxyl functionalized uranium-selective chelating sorbent: simple oxidation of styrene-divinylbenzene copolymer microparticles by Hummers method
文献类型：期刊论文
| 作者 | Liu, Jun ; Li, Juan ; Yang, Xiaodan ; Song, Qiang ; Bai, Chiyao ; Shi, Yong ; Zhang, Lan(张岚） ; Liu, Chunxia（刘春霞） ; Li, Shoujian ; Ma, Lijian |
| 刊名 | MATERIALS LETTERS
 |
| 出版日期 | 2013 |
| 卷号 | 97页码:CONCATENATE(Sheet1!I124,-Sheet1!J124) |
| ISSN号 | 0167-577X |
| 英文摘要 | Hummers method, a classical approach for preparation of graphitic oxide, was employed for the first time to prepare polymer-based uranium selective chelating sorbent by directly oxidizing styrene-divinylbenzene copolymer microparticles synthesized through the mix-solvothermal method in a mild binary solvent system. The resulting material was found rich in phenolic hydroxyl groups (17 mmol/g) using techniques such as FT-IR and XPS. Batch adsorption experiments proved that the chelating sorbent exhibited excellent uranium selectivity from multi-ion solution containing 12 coexisting ions with 0.45 mmol/g of uranium adsorption capacity accounting for up to 52% of the total adsorption capacity, while 373 mg/g of the maximum adsorption capacity for the sorbent was obtained in the "pure" U(VI) ion solution. The proposed method has the advantages of simpleness, cheapness, and high yield of phenolic hydroxyl groups, which could provide a new and generally applicable approach for facile preparation of polyphenolic materials based on phenyl-rich polymer. (C) 2013 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317164600049 |
| 公开日期 | 2014-06-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13748]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Liu, Jun,Li, Juan,Yang, Xiaodan,et al. Facile preparation of polyphenolic hydroxyl functionalized uranium-selective chelating sorbent: simple oxidation of styrene-divinylbenzene copolymer microparticles by Hummers method[J]. MATERIALS LETTERS,2013,97:CONCATENATE(Sheet1!I124,-Sheet1!J124). |
| APA | Liu, Jun.,Li, Juan.,Yang, Xiaodan.,Song, Qiang.,Bai, Chiyao.,...&Ma, Lijian.(2013).Facile preparation of polyphenolic hydroxyl functionalized uranium-selective chelating sorbent: simple oxidation of styrene-divinylbenzene copolymer microparticles by Hummers method.MATERIALS LETTERS,97,CONCATENATE(Sheet1!I124,-Sheet1!J124). |
| MLA | Liu, Jun,et al."Facile preparation of polyphenolic hydroxyl functionalized uranium-selective chelating sorbent: simple oxidation of styrene-divinylbenzene copolymer microparticles by Hummers method".MATERIALS LETTERS 97(2013):CONCATENATE(Sheet1!I124,-Sheet1!J124). |
入库方式： OAI收割
来源：上海应用物理研究所
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