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High-Pressure Stability and Compressibility of Zircon-Type YV1-xPxO4:Eu3+ Solid-Solution Nanoparticles: An X-ray Diffraction and Raman Spectroscopy Study
文献类型：期刊论文
| 作者 | Yuan, Hongsheng ; Wang, Kai ; Li, Shourui ; Tan, Xiao ; Li, Qian ; Yan, Tingting ; Yang, Ke ; Liu, Jing ; Liu, Bingbing ; Zou, Guangtian ; Zou, Bo |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2013 |
| 卷号 | 117期号:36页码:CONCATENATE(Sheet1!I152,-Sheet1!J152) |
| ISSN号 | 1932-7447 |
| 英文摘要 | We probed the high-pressure response of the YV1-xPxO4:Eu3+ (x = 0, 0.5, 0.7, 1.0) solid-solution nanoparticles using angular dispersive synchrotron X-ray diffraction (XRD) and Raman techniques at room temperature. In situ diffraction results showed that the overall nanoparticles underwent an irreversible zircon-to-scheelite structural transformation. The transition pressures were similar to 9.3, similar to 12.1, similar to 14, and similar to 18.4 GPa for the YV1-xPxO4:Eu3+ (x = 0, 0.5, 0.7, 1.0). samples, respectively. Coupled with the zircon-to-scheelite transition features, it was proposed that the transition pressure was probably governed by the stiffness of VO4/PO4 units in the solid solutions. This claim was verified by further Raman measurements, which revealed that the stiffness of VO4/PO4 units was enhanced with increasing P contents. The structural refinements showed that the samples with comparable particle size (20-90 nm) became less compressible with increasing P. content (x 0 -> 0.7 -> 1.0). However, the compressibility of the YV1-xPxO4:Eu3+ sample with smaller particle size (10-30 nm) was similar to that of the YV1-xPxO4:Eu3+ sample. The general compressibility behavior as a function of P content was ascribed to the special packing style related to the stiffness of VO4/PO4 tetrahedra in zircon structure, and the higher surface energy contribution was responsible for the exceptional compressibility in the smaller nanoparticles. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330162700037 |
| 公开日期 | 2014-06-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13769]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Yuan, Hongsheng,Wang, Kai,Li, Shourui,et al. High-Pressure Stability and Compressibility of Zircon-Type YV1-xPxO4:Eu3+ Solid-Solution Nanoparticles: An X-ray Diffraction and Raman Spectroscopy Study[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2013,117(36):CONCATENATE(Sheet1!I152,-Sheet1!J152). |
| APA | Yuan, Hongsheng.,Wang, Kai.,Li, Shourui.,Tan, Xiao.,Li, Qian.,...&Zou, Bo.(2013).High-Pressure Stability and Compressibility of Zircon-Type YV1-xPxO4:Eu3+ Solid-Solution Nanoparticles: An X-ray Diffraction and Raman Spectroscopy Study.JOURNAL OF PHYSICAL CHEMISTRY C,117(36),CONCATENATE(Sheet1!I152,-Sheet1!J152). |
| MLA | Yuan, Hongsheng,et al."High-Pressure Stability and Compressibility of Zircon-Type YV1-xPxO4:Eu3+ Solid-Solution Nanoparticles: An X-ray Diffraction and Raman Spectroscopy Study".JOURNAL OF PHYSICAL CHEMISTRY C 117.36(2013):CONCATENATE(Sheet1!I152,-Sheet1!J152). |
入库方式： OAI收割
来源：上海应用物理研究所
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