Interconvertible Self-Assembly and Rheological Properties of Planar Bilayers and Vesicle Gels in Anionic/Nonionic (CF/CH) Surfactant Solutions
文献类型：期刊论文
| 作者 | Dong, Renhao ; Wu, Jing ; Dong, Shuli ; Song, Shasha ; Tian, Feng ; Hao, Jingcheng |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2013 |
| 卷号 | 8期号:8页码:CONCATENATE(Sheet1!I174,-Sheet1!J174) |
| ISSN号 | 1861-4728; 1861-471X |
| 英文摘要 | The surface and bulk properties of aqueous mixtures of nonionic tetraethylene glycol monododecyl ether (C12EO4) and anionic perfluorolauric acid (PFLA) were studied. These mixtures exhibited pronounced synergistic effects in terms of their mixed micellization and rheological properties. Only one type of mixed micelle is formed in dilute mixed solutions. At low PFLA content, with increasing the total surfactant concentration, short thread-like micelles grow to form larger discs. On increasing the amount of PFLA, owing to the fact that the fluctuant planar bilayers of nonionic C12EO4 become charged, vesicle gels that are comprised of densely packed unilamellar and multilamellar vesicles spontaneously form, in which the fluorocarbon chains in the bilayers are in a fluid state at room temperature. The elastic properties and the yield stress of the lamellar solutions largely increase upon the addition of small amounts of PFLA and they then pass through a maximum at a saturation of effective membrane charge density. Interestingly, increasing the pH value of the gels causes a backward transition from stiff vesicles to flexible planar bilayers. On increasing the amount of NaOH, the bilayers exhibit greater flexibility, owing to the decrease in membrane charges, along with a large decrease in the solution viscosity and their elastic properties. The combination of strong stability of the vesicle gels with the interconvertible transition of bilayers and vesicles is expected to be of practical use for controlled drug delivery and release. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000325926700030 |
| 公开日期 | 2014-06-13 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13787]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Dong, Renhao,Wu, Jing,Dong, Shuli,et al. Interconvertible Self-Assembly and Rheological Properties of Planar Bilayers and Vesicle Gels in Anionic/Nonionic (CF/CH) Surfactant Solutions[J]. CHEMISTRY-AN ASIAN JOURNAL,2013,8(8):CONCATENATE(Sheet1!I174,-Sheet1!J174). |
| APA | Dong, Renhao,Wu, Jing,Dong, Shuli,Song, Shasha,Tian, Feng,&Hao, Jingcheng.(2013).Interconvertible Self-Assembly and Rheological Properties of Planar Bilayers and Vesicle Gels in Anionic/Nonionic (CF/CH) Surfactant Solutions.CHEMISTRY-AN ASIAN JOURNAL,8(8),CONCATENATE(Sheet1!I174,-Sheet1!J174). |
| MLA | Dong, Renhao,et al."Interconvertible Self-Assembly and Rheological Properties of Planar Bilayers and Vesicle Gels in Anionic/Nonionic (CF/CH) Surfactant Solutions".CHEMISTRY-AN ASIAN JOURNAL 8.8(2013):CONCATENATE(Sheet1!I174,-Sheet1!J174). |
入库方式： OAI收割
来源：上海应用物理研究所
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