Manipulating Crystal Orientation of Poly(ethylene oxide) by Nanopores
文献类型:期刊论文
作者 | Guan, Yu ; Liu, Guoming ; Gao, Peiyuan ; Li, Li ; Ding, Guqiao ; Wang, Dujin |
刊名 | ACS MACRO LETTERS
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出版日期 | 2013 |
卷号 | 2期号:3页码:CONCATENATE(Sheet1!I202,-Sheet1!J202) |
ISSN号 | 2161-1653 |
英文摘要 | The confined crystallization behavior of a low molecular weight monodisperse polyethylene oxide (PEO) in anodic alumina oxide (AAO) templates was investigated. Homogeneous nucleation of polymer in AAO templates was confirmed. Within AAO with diameter larger than the contour length of PEO chains, the "kinetics selective growth" crystallization mechanism was confirmed based on the observation that the chain axis preferentially aligned perpendicular to the pore axis. However, when AAO diameter further decreases to a value smaller than the contour length of PEO, unique orientation with chain axis aligned parallel to the pore axis was observed for the first time. The results were discussed based on the competition between thermodynamics and kinetics during the crystallization process. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000316308000002 |
公开日期 | 2014-06-13 |
源URL | [http://ir.sinap.ac.cn/handle/331007/13813] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Guan, Yu,Liu, Guoming,Gao, Peiyuan,et al. Manipulating Crystal Orientation of Poly(ethylene oxide) by Nanopores[J]. ACS MACRO LETTERS,2013,2(3):CONCATENATE(Sheet1!I202,-Sheet1!J202). |
APA | Guan, Yu,Liu, Guoming,Gao, Peiyuan,Li, Li,Ding, Guqiao,&Wang, Dujin.(2013).Manipulating Crystal Orientation of Poly(ethylene oxide) by Nanopores.ACS MACRO LETTERS,2(3),CONCATENATE(Sheet1!I202,-Sheet1!J202). |
MLA | Guan, Yu,et al."Manipulating Crystal Orientation of Poly(ethylene oxide) by Nanopores".ACS MACRO LETTERS 2.3(2013):CONCATENATE(Sheet1!I202,-Sheet1!J202). |
入库方式: OAI收割
来源:上海应用物理研究所
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