BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES
文献类型：期刊论文
| 作者 | 中国科学院兰州化学物理研究所 |
| 刊名 | 中国科学 数学(英文版)
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| 出版日期 | 1979 |
| 卷号 | 12期号:4页码:431-440 |
| ISSN号 | 1674-7283 |
| 中文摘要 | The results of a study of some factors in the preparation of bismuth-molybdate catalyst for the oxidative dehydrogenation of n-butenes is presented briefly in this paper. Kinetic investigation of the relevant reactions over co-gelled and impregnated catalysts suggests that the conversion of butenes and butadiene could be treated as the first order reactions. The complex reactions occurring in the oxidative dehydrogenation of butenes could be adapted into a framework of a simplified reaction scheme, and the kinetic parameters were evaluated for each step in the framework. The physicochemical and catalytic properties of fresh catalyst were investigated and compared with those of deactivated catalyst from commercial reactor, as well as those of specially treated catalysts from a simulated laboratory run in order to have an insight into the cause of catalyst deactivation. A speculation about the nature of active site and reaction mechanism on the catalyst is proposed. |
| 学科主题 | 物理化学 |
| 语种 | 英语 |
| 公开日期 | 2014-06-19 |
| 源URL | [http://210.77.64.217/handle/362003/5780]  |
| 专题 | 兰州化学物理研究所_非现建制 |
| 推荐引用方式 GB/T 7714 | 中国科学院兰州化学物理研究所. BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES[J]. 中国科学 数学(英文版),1979,12(4):431-440. |
| APA | 中国科学院兰州化学物理研究所.(1979).BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES.中国科学 数学(英文版),12(4),431-440. |
| MLA | 中国科学院兰州化学物理研究所."BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES".中国科学 数学(英文版) 12.4(1979):431-440. |
入库方式： OAI收割
来源：兰州化学物理研究所
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