New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane
文献类型:期刊论文
作者 | Pei, Yu-Ning1; Deng, Yu1,2; Li, Jing-Liarig1; Liu, Li1![]() |
刊名 | TETRAHEDRON LETTERS
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出版日期 | 2014-04-30 |
卷号 | 55期号:18页码:2948-2952 |
关键词 | Biscarboline N-O amides Enantioselective reduction Ketoimines Trichlorosilane |
ISSN号 | 0040-4039 |
通讯作者 | Zhu,HJ (reprint author),Hebei Univ,Coll Pharm Sci,Chinese Ctr Chiral,Key Lab Med Chem & Mol Diagnost,Minist Educ,Baoding 071002,Hebei,Peoples R China. ; zhuhuajie@hotmail.com |
英文摘要 | New axial N,N'-dioxide secondary amide derived from r-tryptophan was synthesized and firstly employed in catalytic enantioselective reduction of ketoimines with trichlorosilane. It was found that 4f was an effective catalyst with excellent reactivity and good enantioselectivity. Possible mechanism for the catalytic procedure was tentatively proposed. (C) 2014 Elsevier Ltd. All rights reserved. |
学科主题 | Chemistry |
类目[WOS] | Chemistry, Organic |
研究领域[WOS] | Chemistry |
关键词[WOS] | N-ARYL IMINES ; ASYMMETRIC TRANSFER HYDROGENATION ; RUTHENIUM ; COMPLEXES ; HYDROSILYLATION ; ORGANOCATALYST ; PROPAN-2-OL ; ALDEHYDES ; KETIMINES ; ENAMINES |
收录类别 | SCI ; IC ; CCR |
资助信息 | Hebei University |
语种 | 英语 |
WOS记录号 | WOS:000336114800013 |
公开日期 | 2014-06-23 |
源URL | [http://ir.kib.ac.cn/handle/151853/18110] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Hebei Univ, Coll Pharm Sci, Chinese Ctr Chiral, Key Lab Med Chem & Mol Diagnost,Minist Educ, Baoding 071002, Hebei, Peoples R China 2.Kunming Inst Bot, State Key Lab Photochem & Plant Resources West Ch, Kunming 650204, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Pei, Yu-Ning,Deng, Yu,Li, Jing-Liarig,et al. New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane[J]. TETRAHEDRON LETTERS,2014,55(18):2948-2952. |
APA | Pei, Yu-Ning,Deng, Yu,Li, Jing-Liarig,Liu, Li,&Zhu, Hua-Jie.(2014).New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane.TETRAHEDRON LETTERS,55(18),2948-2952. |
MLA | Pei, Yu-Ning,et al."New chiral biscarboline N,N '-dioxide derivatives as catalyst in enantioselective reduction of ketoimines with trichlorosilane".TETRAHEDRON LETTERS 55.18(2014):2948-2952. |
入库方式: OAI收割
来源:昆明植物研究所
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