Vibrational circular dichroism study for natural bioactive schizandrin and reassignment of its absolute configuration
文献类型：期刊论文
| 作者 | He,Ping ; Wang,Xiangfen ; Guo,Xiujie ; Ji,Yannan ; Zhou,Chuanqi ; Shen,Shigang ; Hu,Dongbao ; Yang,Xiaolong ; Luo,Duqiang ; Dukor,Rina ; Zhu,Huajie |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2014 |
| 卷号 | 55期号:18页码:2965-2968 |
| 关键词 | Absolute configuration Schizandrin VCD ECD DIBENZOCYCLOOCTADIENE LIGNANS (+)-ISOSCHIZANDRIN |
| ISSN号 | 0040-4039 |
| 通讯作者 | Zhu,HJ (reprint author),Hebei Univ,Coll Pharm Sci,Chinese Ctr Chiral,Key Lab Med Chem & Mol Diagnost,Educ Minist China,Baoding 071002,Peoples R China. ; hjzhu@mail.kib.ac.cn |
| 英文摘要 | Bioactive natural product (+)-schizandrin was assigned as (7S,8S) using NMR. Recently, we obtained (+)schizandrin from TCM Schisandra sphenanthera Rehd. et Wils. Its planar structure was well established using NMR and HR-MS including the reported references. Its absolute configuration is assigned using vibrational circular dichroism (VCD). By careful VCD investigation of (75,8S) and (75,8R) using B3LYP/6-311+G(d) methods, absolute configuration of (+)-schizandrin is assigned as (7S,8R). Electronic circular dichroism (ECD) was used for the discussion too and it gave the same conclusion. (C) 2014 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | Hebei University; National Natural Science Foundation of China (NSFC) [21202033]; Natural Science Foundation of Hebei Province [C2012201047]; Foundation of Hebei University [179] |
| 语种 | 英语 |
| 公开日期 | 2014-06-23 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/18111]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 推荐引用方式 GB/T 7714 | He,Ping,Wang,Xiangfen,Guo,Xiujie,et al. Vibrational circular dichroism study for natural bioactive schizandrin and reassignment of its absolute configuration[J]. TETRAHEDRON LETTERS,2014,55(18):2965-2968. |
| APA | He,Ping.,Wang,Xiangfen.,Guo,Xiujie.,Ji,Yannan.,Zhou,Chuanqi.,...&Zhu,Huajie.(2014).Vibrational circular dichroism study for natural bioactive schizandrin and reassignment of its absolute configuration.TETRAHEDRON LETTERS,55(18),2965-2968. |
| MLA | He,Ping,et al."Vibrational circular dichroism study for natural bioactive schizandrin and reassignment of its absolute configuration".TETRAHEDRON LETTERS 55.18(2014):2965-2968. |
入库方式： OAI收割
来源：昆明植物研究所
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