A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei
文献类型：期刊论文
| 作者 | Zhu, Hucheng1; Huan, Lijun2; Chen, Chunmei1; Yang, Jing3 ; He, Jiangbo4; Chen, Yong2; Yao, Guangmin1; Luo, Zengwei1; Xue, Yongbo1; Zhang, Yonghui1
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| 刊名 | TETRAHEDRON LETTERS
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| 出版日期 | 2014-04-02 |
| 卷号 | 55期号:14页码:2277-2279 |
| 关键词 | Clerodendrum bungei Enantiomer X-ray ECD |
| ISSN号 | 0040-4039 |
| 通讯作者 | Xue,YB (reprint author),Huazhong Univ Sci & Technol,Tongi Med Coll,Sch Pharm,Hubei Key Lab Nat Med Chem & Resource Evaluat,Wuhan 430030,Peoples R China. ; yongboxue@mail.hust.edu.cn ; zhangyh@mails.tjmu.edu.cn |
| 英文摘要 | A pair of unprecedented enantiomers (1a/1b) of cyclohexylethanoid bearing an unusual trioxabicyclo[4.2.1]nonane ring, along with two known structurally related cyclohexylethanoids, (+)-rengyolone (2) and cleroindicin E (3), were isolated from the aerial parts of Clerodendrum bungei. The structures and absolute configurations of the enantiomers were determined by comprehensive spectroscopic analysis, single-crystal X-ray diffraction, and quantum mechanical calculation of the electronic circular dichroic (ECD) spectra. The postulated biogenetic pathway of 1a/1b was also discussed. (C) 2014 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | GLYCOLALDEHYDE ; DITERPENOIDS ; CONSTITUENTS |
| 收录类别 | SCI ; IC |
| 资助信息 | Program for New Century Excellent Talents in University, State Education Ministry of China [NCET-2008-0224] |
| 语种 | 英语 |
| WOS记录号 | WOS:000334817900026 |
| 公开日期 | 2014-06-23 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/18129]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Tongi Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Peoples R China 2.Hubei Univ, Coll Life Sci, Wuhan 430062, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China 4.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Hucheng,Huan, Lijun,Chen, Chunmei,et al. A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei[J]. TETRAHEDRON LETTERS,2014,55(14):2277-2279. |
| APA | Zhu, Hucheng.,Huan, Lijun.,Chen, Chunmei.,Yang, Jing.,He, Jiangbo.,...&Zhang, Yonghui.(2014).A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei.TETRAHEDRON LETTERS,55(14),2277-2279. |
| MLA | Zhu, Hucheng,et al."A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei".TETRAHEDRON LETTERS 55.14(2014):2277-2279. |
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来源：昆明植物研究所
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