Henry's law constant for phosphine in seawater: determination and assessment of influencing factors
文献类型：期刊论文
| 作者 | Fu Mei1,2; Yu Zhiming1 ; Lu Guangyuan1,2; Song Xiuxian1; Song, XX
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| 刊名 | CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY
 |
| 出版日期 | 2013-07-01 |
| 卷号 | 31期号:4页码:860-866 |
| 关键词 | phosphine Henry's Law constant seawater influencing factors multiple phase equilibration |
| ISSN号 | 0254-4059 |
| 通讯作者 | Song, XX |
| 中文摘要 | The Henry's Law constant (k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature (approximately 23A degrees C). This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry's Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus. |
| 英文摘要 | The Henry's Law constant (k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature (approximately 23A degrees C). This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry's Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus. |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences |
| 学科主题 | Marine & Freshwater Biology ; Oceanography |
| 类目[WOS] | Limnology ; Oceanography |
| 研究领域[WOS] | Marine & Freshwater Biology ; Oceanography |
| 关键词[WOS] | MATRIX-BOUND PHOSPHINE ; MULTIPLE PHASE EQUILIBRATION ; CHINA ; GAS ; PHOSPHORUS ; WATER ; LAKE ; TEMPERATURES ; HYDROSPHERE ; TROPOSPHERE |
| 收录类别 | SCI |
| 原文出处 | 10.1007/s00343-013-2212-1 |
| 语种 | 英语 |
| WOS记录号 | WOS:000321629400018 |
| 公开日期 | 2014-07-17 |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/16476]  |
| 专题 | 海洋研究所_海洋生态与环境科学重点实验室 |
| 通讯作者 | Song, XX |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Ecol & Environm Sci, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu Mei,Yu Zhiming,Lu Guangyuan,et al. Henry's law constant for phosphine in seawater: determination and assessment of influencing factors[J]. CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY,2013,31(4):860-866. |
| APA | Fu Mei,Yu Zhiming,Lu Guangyuan,Song Xiuxian,&Song, XX.(2013).Henry's law constant for phosphine in seawater: determination and assessment of influencing factors.CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY,31(4),860-866. |
| MLA | Fu Mei,et al."Henry's law constant for phosphine in seawater: determination and assessment of influencing factors".CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY 31.4(2013):860-866. |
入库方式： OAI收割
来源：海洋研究所
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