Longphyllinesides A and B: natural Diels-Alder adducts from Daphniphyllum longeracemosum?
文献类型：期刊论文
| 作者 | Di, Ying-Tong1 ; Wee, Chorng-Shin2; Li, Chun-Shun1; Kong, Ning-Chuan4; Wang, Jun-Song1; Fang, Xin1; Zhu, Hua-Jie1; Wu, Yun-Dong2,3; Hao, Xiao-Jiang1
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| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 70期号:26页码:4017-4021 |
| 关键词 | Daphniphyllum longeracemosum Alkaloid Biogenetic pathway Chemical computation Diels-Alderase |
| ISSN号 | 0040-4020 |
| 通讯作者 | Zhu,HJ (reprint author),Chinese Acad Sci,Kunming Inst Bot,State Key Lab Phytochem & Plant Resources West Ch,Kunming 650201,Yunnan,Peoples R China. ; hjzhu@mail.kib.ac.cn ; hydwu@ust.hk ; haoxj@mail.kib.ac.cn |
| 英文摘要 | Two new alkaloids, longphyllinesides A (1) and B (2), were isolated from Daphniphyllum longeracemosum. Their structures were elucidated using 1D and 2D NMR spectra. The key step in their biogenetic pathway is indicated to be Diels-Alder cycloaddition via asynchronous concerted mechanism by density functional theory calculations. The possibility of involvement of a Diels-Alderase is also discussed. (C) 2014 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry, Organic |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | NATURALLY-OCCURRING IRIDOIDS ; ADIABATIC CONNECTION ; MECHANISTIC INSIGHTS ; TRANSITION-STATE ; ALKALOIDS ; CASCADE ; CYCLOADDITION ; BIOSYNTHESIS ; ENERGIES ; SYNTHASE |
| 收录类别 | SCI ; IC |
| 资助信息 | Young Academic and Technical Leader Raising Foundation of Yunnan Province [2009CI072];Chinese Academy of Sciences XiBuZhiGuang Project;HPC Center of Kunming Institute of Botany, CAS |
| 语种 | 英语 |
| WOS记录号 | WOS:000337209500010 |
| 公开日期 | 2014-07-28 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/18183]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Hong Kong Univ Sci & Technol, Kowloon, Hong Kong, Peoples R China 3.Peking Univ, Shenzhen Grad Sch, Lab Chem Gen, Shenzhen 518055, Peoples R China 4.Yunnan Acad Tobacco Sci, Kunming 650106, Yunnan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Di, Ying-Tong,Wee, Chorng-Shin,Li, Chun-Shun,et al. Longphyllinesides A and B: natural Diels-Alder adducts from Daphniphyllum longeracemosum?[J]. TETRAHEDRON,2014,70(26):4017-4021. |
| APA | Di, Ying-Tong.,Wee, Chorng-Shin.,Li, Chun-Shun.,Kong, Ning-Chuan.,Wang, Jun-Song.,...&Hao, Xiao-Jiang.(2014).Longphyllinesides A and B: natural Diels-Alder adducts from Daphniphyllum longeracemosum?.TETRAHEDRON,70(26),4017-4021. |
| MLA | Di, Ying-Tong,et al."Longphyllinesides A and B: natural Diels-Alder adducts from Daphniphyllum longeracemosum?".TETRAHEDRON 70.26(2014):4017-4021. |
入库方式： OAI收割
来源：昆明植物研究所
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