Dendritic [2]Rotaxanes: Synthesis, Characterization, and Properties
文献类型：期刊论文
| 作者 | Liu, Guoxing1; Li, Ziyong1; Wu, Di1; Xue, Wen1; Li, Tingting2; Liu, Sheng Hua1; Yie, Jun1 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-01-17 |
| 卷号 | 79期号:2页码:643-652 |
| ISSN号 | 0022-3263 |
| 通讯作者 | Liu, SH (reprint author), Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China. |
| 中文摘要 | A series of dendritic ammonium salts have been designed and synthesized. Subsequently, they were used to construct the corresponding [2]rotaxanes by a template-directed clipping approach. Unusually, two unsymmetrical dendritic [2]rotaxanes containing fluorophore (pyrene units) were also obtained; their optical properties, such as UV/vis absorption and fluorescence, were measured. The results indicate that these two rotaxanes possess stronger intermolecular interaction in the solid state than in solution. As a result, solutions of high concentration readily formed the excimer. These special rotaxanes might be applied in dynamic fluorescence-reponsive materials, and the rotaxane structure will also be used as a strategy to adjust the aggregated behaviors of fluorescent molecules. |
| 英文摘要 | A series of dendritic ammonium salts have been designed and synthesized. Subsequently, they were used to construct the corresponding [2]rotaxanes by a template-directed clipping approach. Unusually, two unsymmetrical dendritic [2]rotaxanes containing fluorophore (pyrene units) were also obtained; their optical properties, such as UV/vis absorption and fluorescence, were measured. The results indicate that these two rotaxanes possess stronger intermolecular interaction in the solid state than in solution. As a result, solutions of high concentration readily formed the excimer. These special rotaxanes might be applied in dynamic fluorescence-reponsive materials, and the rotaxane structure will also be used as a strategy to adjust the aggregated behaviors of fluorescent molecules. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TEMPLATE-DIRECTED SYNTHESIS ; MECHANICALLY INTERLOCKED DENDRIMERS ; THERMODYNAMIC CONTROL ; MOLECULAR MACHINES ; BRANCHING MOTIFS ; CHEMISTRY ; FLUORESCENT ; POLYMERS ; DENDRONS ; COOPERATIVITY |
| 收录类别 | SCI ; IC |
| 资助信息 | National Natural Science Foundation of China [20931006, 21072070, 21272088]; Program for Academic Leader in Wuhan Municipality [201271130441]; Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education; Natural Science Foundation of Hubei Province [2013CFB207]; Central China Normal University [CCNU13T04095] |
| 语种 | 英语 |
| WOS记录号 | WOS:000330099000017 |
| 公开日期 | 2014-08-13 |
| 源URL | [http://ir.ihb.ac.cn/handle/342005/20124]  |
| 专题 | 水生生物研究所_分析测试中心_期刊论文 |
| 作者单位 | 1.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China 2.Chinese Acad Sci, Inst Hydrobiol, Wuhan 430079, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Guoxing,Li, Ziyong,Wu, Di,et al. Dendritic [2]Rotaxanes: Synthesis, Characterization, and Properties[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(2):643-652. |
| APA | Liu, Guoxing.,Li, Ziyong.,Wu, Di.,Xue, Wen.,Li, Tingting.,...&Yie, Jun.(2014).Dendritic [2]Rotaxanes: Synthesis, Characterization, and Properties.JOURNAL OF ORGANIC CHEMISTRY,79(2),643-652. |
| MLA | Liu, Guoxing,et al."Dendritic [2]Rotaxanes: Synthesis, Characterization, and Properties".JOURNAL OF ORGANIC CHEMISTRY 79.2(2014):643-652. |
入库方式： OAI收割
来源：水生生物研究所
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