Catalytic upgrading of coal pyrolysis tar over char-based catalysts
文献类型：期刊论文
| 作者 | Han, Jiangze1,2; Wang, Xingdong1; Yue, Junrong1; Gao, Shiqiu1; Xu, Guangwen1 |
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 122期号:1页码:98-106 |
| 关键词 | Coal pyrolysis Catalytic upgrading Tar quality Char-based catalyst |
| ISSN号 | 0378-3820 |
| 其他题名 | Fuel Process. Technol. |
| 中文摘要 | Catalytic upgrading of coal pyrolysis tar was investigated in a dual-stage reactor over char and metal-impregnated char (Co-char, Ni-char, Cu-char, Zn-char). The catalytic upgrading caused the lower total tar yield and the higher non-condensable gas yield but the fraction of light tar (boiling point <360 degrees C) obviously increased to allow slightly higher total yield of light tar. When the catalytic upgrading was at 600 degrees C over a layer of char having a mass of 20% of the tested coal, the resulting light tar fraction in the tar increased by 25% in comparison with the coal pyrolysis only at 600 degrees C Over the metal-impregnated char, which was 5% of the tested coal in mass, good upgrading effect was obtained at 500 degrees C. The catalytic tar-upgrading activity decreased in an order of Co-char > Ni-char > Cu-char > Zn-char, and over Ni-char the realized light tar yield and its content in the tar increased by 17.2% and 32.7%, respectively. The upgrading effect also lowered the contents of element N and S in the resulting tar by 45.6% and 43.5%, respectively. NH3-TPD clarified that the order in acidity of the char-based catalysts was the same as for the upgrading activity shown above. (C) 2014 Elsevier B.V. All rights reserved. |
| 英文摘要 | Catalytic upgrading of coal pyrolysis tar was investigated in a dual-stage reactor over char and metal-impregnated char (Co-char, Ni-char, Cu-char, Zn-char). The catalytic upgrading caused the lower total tar yield and the higher non-condensable gas yield but the fraction of light tar (boiling point <360 degrees C) obviously increased to allow slightly higher total yield of light tar. When the catalytic upgrading was at 600 degrees C over a layer of char having a mass of 20% of the tested coal, the resulting light tar fraction in the tar increased by 25% in comparison with the coal pyrolysis only at 600 degrees C Over the metal-impregnated char, which was 5% of the tested coal in mass, good upgrading effect was obtained at 500 degrees C. The catalytic tar-upgrading activity decreased in an order of Co-char > Ni-char > Cu-char > Zn-char, and over Ni-char the realized light tar yield and its content in the tar increased by 17.2% and 32.7%, respectively. The upgrading effect also lowered the contents of element N and S in the resulting tar by 45.6% and 43.5%, respectively. NH3-TPD clarified that the order in acidity of the char-based catalysts was the same as for the upgrading activity shown above. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
| 关键词[WOS] | BIOMASS GASIFICATION GAS ; VICTORIAN BROWN-COAL ; AROMATIC-HYDROCARBONS ; VOLATILE MATTER ; NI CATALYSTS ; ZIRCONIA ; LIGNITE ; VOLATILIZATION ; HYDROCRACKING ; REDUCTION |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000333999700012 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10909]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Jiangze,Wang, Xingdong,Yue, Junrong,et al. Catalytic upgrading of coal pyrolysis tar over char-based catalysts[J]. FUEL PROCESSING TECHNOLOGY,2014,122(1):98-106. |
| APA | Han, Jiangze,Wang, Xingdong,Yue, Junrong,Gao, Shiqiu,&Xu, Guangwen.(2014).Catalytic upgrading of coal pyrolysis tar over char-based catalysts.FUEL PROCESSING TECHNOLOGY,122(1),98-106. |
| MLA | Han, Jiangze,et al."Catalytic upgrading of coal pyrolysis tar over char-based catalysts".FUEL PROCESSING TECHNOLOGY 122.1(2014):98-106. |
入库方式： OAI收割
来源：过程工程研究所
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