Extraction of vanadium from chloride solution with high concentration of iron by solvent extraction using D2EHPA
文献类型：期刊论文
| 作者 | Hu, Guoping1,2,3; Chen, Desheng1,3; Wang, Lina1,3; Liu, JingChong1,2,3; Zhao, Hongxin1,3; Liu, Yahui1,3; Qi, Tao1,3; Zhang, Changqiao2; Yu, Ping2 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2014-04-07 |
| 卷号 | 125期号:1页码:59-65 |
| 关键词 | Reduced vanadium-bearing titanomagnetite concentrate Chloride solution Vanadium Solvent extraction Bis (2-ethylhexyl) phosphoric acid |
| ISSN号 | 1383-5866 |
| 其他题名 | Sep. Purif. Technol. |
| 中文摘要 | Vanadium (IV) bearing chloride solution with the Fe (II)/V (IV) mass ratio of 60 was prepared to simulate the acidic liquor by hydrochloric acid leaching of reduced vanadium-bearing titanomagnetite. Extractant of bis (2-ethylhexyl) phosphoric acid (D2EHPA) was used to extract vanadium from the solution. Under the optimal extraction conditions of equilibrium H+ concentration of 0.27-0.42 mol/L, D2EHPA concentration (v/v, diluted in n-heptane) of 10%, extraction temperature of 20-25 degrees C, equilibrium time of 60 min, phase ratio (O/A) of 1:1, more than 99% of vanadium can be extracted. Loaded organic phase were stripped by dilute H2SO4 solution under the optimal stripping conditions of H2SO4 concentration of 20 wt.%, phase ratio (O/A) of 10:1, stripping time of 120 min, and 98% of vanadium can be stripped. The concentrations of V and Fe in the stripping solution were 13.0 g/L and 3.9 g/L, respectively. V2O5 products with purity of 99.2% were obtained after oxidation, precipitation and calcination. The overall separation coefficient of V and Fe was 200. Experimental results indicated that V (IV) can be also separated from other metal ions such as Mg (II), Ni (II), Zn (II), Ca (II), Al (III) and Cu (II) in the chloride solution. A flow sheet on the recovery of vanadium from vanadium-bearing chloride solution containing high concentration of iron was proposed. (C) 2014 Elsevier B.V. All rights reserved. |
| 英文摘要 | Vanadium (IV) bearing chloride solution with the Fe (II)/V (IV) mass ratio of 60 was prepared to simulate the acidic liquor by hydrochloric acid leaching of reduced vanadium-bearing titanomagnetite. Extractant of bis (2-ethylhexyl) phosphoric acid (D2EHPA) was used to extract vanadium from the solution. Under the optimal extraction conditions of equilibrium H+ concentration of 0.27-0.42 mol/L, D2EHPA concentration (v/v, diluted in n-heptane) of 10%, extraction temperature of 20-25 degrees C, equilibrium time of 60 min, phase ratio (O/A) of 1:1, more than 99% of vanadium can be extracted. Loaded organic phase were stripped by dilute H2SO4 solution under the optimal stripping conditions of H2SO4 concentration of 20 wt.%, phase ratio (O/A) of 10:1, stripping time of 120 min, and 98% of vanadium can be stripped. The concentrations of V and Fe in the stripping solution were 13.0 g/L and 3.9 g/L, respectively. V2O5 products with purity of 99.2% were obtained after oxidation, precipitation and calcination. The overall separation coefficient of V and Fe was 200. Experimental results indicated that V (IV) can be also separated from other metal ions such as Mg (II), Ni (II), Zn (II), Ca (II), Al (III) and Cu (II) in the chloride solution. A flow sheet on the recovery of vanadium from vanadium-bearing chloride solution containing high concentration of iron was proposed. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | IV EXTRACTION ; FLY-ASH ; RECOVERY ; ACID ; COAL ; OIL ; MOLYBDENUM ; REDUCTION ; KINETICS ; TITANIUM |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000335432300007 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10911]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Guoping,Chen, Desheng,Wang, Lina,et al. Extraction of vanadium from chloride solution with high concentration of iron by solvent extraction using D2EHPA[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2014,125(1):59-65. |
| APA | Hu, Guoping.,Chen, Desheng.,Wang, Lina.,Liu, JingChong.,Zhao, Hongxin.,...&Yu, Ping.(2014).Extraction of vanadium from chloride solution with high concentration of iron by solvent extraction using D2EHPA.SEPARATION AND PURIFICATION TECHNOLOGY,125(1),59-65. |
| MLA | Hu, Guoping,et al."Extraction of vanadium from chloride solution with high concentration of iron by solvent extraction using D2EHPA".SEPARATION AND PURIFICATION TECHNOLOGY 125.1(2014):59-65. |
入库方式： OAI收割
来源：过程工程研究所
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